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Molecular and Ionic Solids02:54

Molecular and Ionic Solids

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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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Ionic Radii03:10

Ionic Radii

33.8K
Ionic radius is the measure used to describe the size of an ion. A cation always has fewer electrons and the same number of protons as the parent atom; it is smaller than the atom from which it is derived. For example, the covalent radius of an aluminum atom (1s22s22p63s23p1) is 118 pm, whereas the ionic radius of an Al3+ (1s22s22p6) is 68 pm. As electrons are removed from the outer valence shell, the remaining core electrons occupying smaller shells experience a greater effective nuclear...
33.8K
Ionic Bonds00:42

Ionic Bonds

131.7K
Overview
When atoms gain or lose electrons to achieve a more stable electron configuration they form ions. Ionic bonds are electrostatic attractions between ions with opposite charges. Ionic compounds are rigid and brittle when solid and may dissociate into their constituent ions in water. Covalent compounds, by contrast, remain intact unless a chemical reaction breaks them.
Opposing Charges Hold Ions Together in Ionic Compounds
Ionic bonds are reversible electrostatic interactions between ions...
131.7K
Solubility of Ionic Compounds02:55

Solubility of Ionic Compounds

68.3K
Solubility is the measure of the maximum amount of solute that can be dissolved in a given quantity of solvent at a given temperature and pressure. Solubility is usually measured in molarity (M) or moles per liter (mol/L). A compound is termed soluble if it dissolves in water.
68.3K
Ionic Crystal Structures02:42

Ionic Crystal Structures

17.7K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
17.7K
Ionic Compounds: Formulas and Nomenclature03:34

Ionic Compounds: Formulas and Nomenclature

88.1K
An element composed of atoms that readily lose electrons (a metal) can react with an element composed of atoms that readily gain electrons (a nonmetal) to produce ions through complete electron transfer. The compound formed by this transfer is stabilized by the electrostatic attractions (ionic bonds) between the oppositely charged ions.
88.1K

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Video Experimental Relacionado

Updated: Feb 12, 2026

Pretreatment of Lignocellulosic Biomass with Low-cost Ionic Liquids
10:42

Pretreatment of Lignocellulosic Biomass with Low-cost Ionic Liquids

Published on: August 10, 2016

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Líquido iónico diseñado para mejorar la conductividad PEDOT:PSS

Ambroise de Izarra1,2, Seongjin Park1, Jinhee Lee1

  • 1Department of Energy Science and Engineering , DGIST , Daegu 42988 , Korea.

Journal of the American Chemical Society
|April 11, 2018
PubMed
Resumen
Este resumen es generado por máquina.

Los líquidos iónicos mejoran la conductividad del poliestireno sulfonato (PEDOT:PSS) promoviendo el intercambio iónico y el crecimiento del dominio PEDOT. Los líquidos iónicos más efectivos facilitan el intercambio iónico eficiente y mantienen portadores de carga uniformes para una mejor conductividad.

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Área de la Ciencia:

  • Ciencias de los materiales
  • Química de los polímeros
  • Química computacional

Sus antecedentes:

  • El poli-3,4-etilendioxitiofeno: poliestirenesulfonato (PEDOT:PSS) es un polímero conductor prometedor para la electrónica flexible.
  • Su conductividad está limitada por las capas aislantes de poliestirenesulfonato (PSS) que rodean los núcleos conductores de poli-3,4-etilendioxitofeno (PEDOT).
  • Los líquidos iónicos (IL) han demostrado potencial para mejorar la conductividad PEDOT:PSS, pero el mecanismo sigue sin estar claro.

Objetivo del estudio:

  • Para aclarar el mecanismo por el cual los líquidos iónicos mejoran la conductividad PEDOT:PSS.
  • Establecer un principio de diseño para líquidos iónicos de alto rendimiento para aplicaciones PEDOT:PSS.
  • Identificar nuevos líquidos iónicos candidatos para mejorar la conductividad.

Principales métodos:

  • Cálculos de energía libre de la teoría funcional de la densidad (DFT) en modelos mínimos PEDOT:PSS.
  • Simulaciones de dinámica molecular en modelos PEDOT:PSS más grandes en solución.
  • Análisis de la eficiencia del intercambio iónico, la morfología PEDOT y la distribución del portador de carga.

Principales resultados:

  • Las IL más efectivas son aquellas con las energías de enlace más bajas, facilitando el intercambio iónico eficiente.
  • El intercambio iónico conduce al desacoplamiento PEDOT de PSS, formando dominios PEDOT conductores a gran escala decorados por aniones IL.
  • Los aniones IL óptimos mantienen una distribución uniforme del portador de carga a lo largo de la columna vertebral PEDOT, mejorando la conductividad.

Conclusiones:

  • Los IL de alto rendimiento deben promover un intercambio iónico eficiente para mejorar la morfología PEDOT y un p-dopaje uniforme de alto nivel para mejorar la conductividad intrínseca.
  • Se propone un nuevo par de IL con propiedades específicas de extracción de electrones, voluminosas, blandas e hidrofóbicas basadas en estos principios.