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Hidrotiolación catalítica: Regioselectividad controlada por el contador

Xiao-Hui Yang1, Ryan T Davison1, Shao-Zhen Nie1,2

  • 1Department of Chemistry , University of California , Irvine , California 92697 , United States.

Journal of the American Chemical Society
|February 9, 2019
PubMed
Resumen

Este estudio detalla la hidrotiolación catalítica de dienos, controlando la regioselectividad con los counteriones de rodio. Este método permite la primera síntesis enantioselectiva de (-) -agelasidina A a partir del β-farneseno.

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