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Nomenclature of Alkenes02:29

Nomenclature of Alkenes

The IUPAC naming system for alkenes replaces -an- with -en- in the corresponding parent alkanes. Accordingly, a simple alkene replaces the -ane suffix of the alkane with -ene.
As per the IUPAC rules, the longest carbon chain containing the maximum number of double bonds is identified as the parent chain and is numbered such that the doubly bonded carbon atoms receive the lowest possible numbers. The location of the double bond is indicated by the number of its first carbon atom. In branched...
Nomenclature of Alkynes02:39

Nomenclature of Alkynes

Alkynes are unsaturated hydrocarbons characterized by the presence of carbon-carbon triple bonds and have a general formula CnH2n-2. The nomenclature of alkynes follows a set of rules similar to alkanes and alkenes; however, alkynes bear the suffix "-yne" instead of "-ane" or "-ene." There are two approaches to naming alkynes:
Structure of Conjugated Dienes01:16

Structure of Conjugated Dienes

Introduction
Conjugated dienes are compounds characterized by the presence of alternating double and single bonds. In a conjugated system like 1,3-butadiene, the unhybridized 2p orbital on each carbon overlaps continuously, allowing the π electrons to be delocalized across the entire molecule. In contrast, this type of overlap does not occur in cumulated and isolated dienes, such as 2,3-pentadiene and 1,4-pentadiene, respectively. Instead, the π electrons remain localized between the double...
Aromatic Hydrocarbon Anions: Structural Overview01:18

Aromatic Hydrocarbon Anions: Structural Overview

Neutral hydrocarbons like cyclopentadiene with an odd number of carbon atoms and one intervening CH2 group in the ring are not aromatic. Cyclopentadiene with 4 π electrons does not satisfy the 4n + 2 π electron rule. Additionally, the intervening CH2 group is sp3 hybridized and lacks a vacant p orbital, thereby interrupting the overlap of p orbitals in a continuous manner and preventing the delocalization of π electrons throughout the ring.
Due to the absence of continuous overlap of p...
Aryldiazonium Salts to Azo Dyes: Diazo Coupling01:11

Aryldiazonium Salts to Azo Dyes: Diazo Coupling

The reaction of weakly electrophilic aryldiazonium (also called arenediazonium) salts with highly activated aromatic compounds leads to the formation of products with an —N=N— link, called an azo linkage. This reaction, presented in Figure 1, is known as diazo coupling and occurs without the loss of the nitrogen atoms of the aryldiazonium salt. Highly activated aromatic compounds such as phenols or arylamines favor the diazo coupling reaction. The coupling generally occurs at the para position.
Characteristics and Nomenclature of Copolymers01:24

Characteristics and Nomenclature of Copolymers

Copolymers are the products obtained from the polymerization of multiple monomer species. So, in a polymer chain itself, there can be multiple repeating units that come from different monomers. The process of synthesizing a polymer from different monomer species is called copolymerization. When two monomers are involved, the polymer is known as a bipolymer. Polymers with three and four monomers are termed terpolymers and quaterpolymers, respectively. Figure 1 depicts the copolymerization of...

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Video Experimental Relacionado

Updated: Jun 18, 2026

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
09:35

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

Corannurylene Pentapetalae, también conocido como Corannurylene

Dong Meng1,2, Guogang Liu2,3, Chengyi Xiao4

  • 1Key Laboratory of Organic Optoelectronics and Molecular Engineering, Department of Chemistry , Tsinghua University , Beijing 100084 , China.

Journal of the American Chemical Society
|March 9, 2019
PubMed
Resumen
Este resumen es generado por máquina.

Los investigadores sintetizaron un nuevo grafenoide no plano, corannurileno pentapetalae (CRP), utilizando fragmentos de perileno diimida (PDI) y un núcleo de corannuleno. La estructura simétrica D5 muestra potencial para el transporte de electrones a través de su red única de panal.

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Catalytic Scavenging of Plant Reactive Oxygen Species In Vivo by Anionic Cerium Oxide Nanoparticles
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1,3,5-Triphenylbenzene and Corannulene as Electron Receptors for Lithium Solvated Electron Solutions
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Área de la Ciencia:

  • Ciencias de los materiales
  • Química orgánica
  • Nanotecnología

Sus antecedentes:

  • Existen avances significativos en la síntesis de grafenoides no planos.
  • Los desafíos permanecen en la comprensión de las relaciones estructura-propiedad, particularmente las interacciones intermoleculares.

Objetivo del estudio:

  • Para presentar un nuevo grafenoide no plano, el corannurylene pentapetalae (CRP).
  • Investigar las características estructurales y las interacciones intermoleculares de la CRP.
  • Explorar el potencial del CRP en los dispositivos electrónicos.

Principales métodos:

  • Síntesis de abajo hacia arriba que incluye fragmentos planos de perilenodiimida (PDI) y un núcleo curvo de corannuleno.
  • Difracción de rayos X de cristal único para elucidación estructural.
  • Fabricación y ensayo de dispositivos de transistores.

Principales resultados:

  • Se identificaron dos estructuras distintas de CRP: D5-simétrica y C2-simétrica.
  • El CRP D5-simétrico exhibe una red de nido de abeja quiral única y apilada alternativamente.
  • El CRP simétrico C2 forma unidades de dímeros a través del apilamiento π-π.
  • Los dispositivos de transistores mostraron que la red de nido de abeja del CRP simétrico D5 facilita el transporte de electrones incluso sin apilamiento π-π.

Conclusiones:

  • Corannurylene pentapetalae (CRP) representa una nueva clase de grafenoides no planas.
  • La estructura de nido de abeja del CRP D5-simétrico es prometedora para aplicaciones de transporte de electrones.
  • Este trabajo avanza en la comprensión de las relaciones estructura-propiedad en grafenoides complejos.