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El futuro de los copolímeros supramoleculares revelado por la reflexión sobre la copolimización covalente
Beatrice Adelizzi, Nathan J Van Zee1, Lafayette N J de Windt
1Chimie Moléculaire, Macromoléculaire, et Matériaux, École Supérieure de Physique et de Chimie Industrielles de la Ville de Paris (ESPCI)-CNRS, UMR-7167 , Paris Sciences et Lettres (PSL) Research University , 10 Rue Vauquelin , 75005 Paris , France.
Journal of the American Chemical Society
|March 20, 2019
Resumen
Los copolímeros supramoleculares ofrecen funcionalidades dinámicas, pero controlar su microestructura sigue siendo un desafío. Esta perspectiva describe los principios para analizar y diseñar estos materiales avanzados comparándolos con la copolimización covalente.
Área de la Ciencia:
- Ciencias de los materiales
- Química de los polímeros
Sus antecedentes:
- Los copolímeros supramoleculares son una clase emergente de materiales con un potencial demostrado.
- Estos polímeros no covalentes integran múltiples componentes, ofreciendo dinámica y nuevas funcionalidades.
- Sin embargo, el control preciso de su microestructura es un desafío significativo.
Objetivo del estudio:
- Establecer los principios generales para la copolimización supramolecular.
- Analizar la copolimización supramolecular utilizando los conceptos de copolimización covalente establecidos.
- Proporcionar directrices para la clasificación y diseño de sistemas supramoleculares multicomponentes.
Principales métodos:
- Análisis comparativo de la copolimización supramolecular y covalente.
- Revisión de la literatura y desarrollo del marco teórico.
- Definición de las directrices de clasificación y diseño.
Principales resultados:
- Se propone un marco para comprender los principios de la copolimización supramolecular.
- Se destacan las analogías y diferencias entre los enfoques covalentes y supramoleculares.
- Se sugieren directrices para el control de la microestructura y el diseño de los materiales.
Conclusiones:
- El puente de la comprensión entre la copolimización covalente y supramolecular es crucial.
- La clasificación y el análisis sistemáticos acelerarán el diseño de materiales supramoleculares avanzados.
- Esta perspectiva proporciona una base para futuras investigaciones en sistemas supramoleculares multicomponentes.
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