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Metallic Solids02:37

Metallic Solids

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
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Thermal Expansion01:22

Thermal Expansion

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The expansion of alcohol in a thermometer is one of many commonly encountered examples of thermal expansion, which is the change in size or volume of a given system as its temperature changes. The most visible example is the expansion of hot air. When air is heated, it expands and becomes less dense than the surrounding air, which then exerts an upward force on the hot air to, for example, make steam and smoke rise, and hot air balloons float. The same behavior happens in all liquids and gases,...
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Thermal expansion and Thermal stress: Problem Solving01:27

Thermal expansion and Thermal stress: Problem Solving

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San Francisco's Golden Gate Bridge is exposed to temperatures ranging from -15 °C to 40 °C. At its coldest, the main span of the bridge is 1275 m long. Assuming that the bridge is made entirely of steel, what is the change in its length between these temperatures?
To solve the problem, first, identify the known and unknown quantities. The initial length (L) of the bridge is 1275 m, the coefficient of linear expansion (α) for steel is 12 x 10-6/°C, and the change in temperature (ΔT) is 55...
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Recrystallization: Solid–Solution Equilibria01:10

Recrystallization: Solid–Solution Equilibria

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Recrystallization is a purification technique used to separate impurities from solid compounds. In this technique, no chemical reactions occur. Instead, it exploits physical properties only, specifically, the solubility differences between the desired compound and impurities, either at a single temperature or at different temperatures, and under other selected conditions. The solid-solution equilibrium (solubility equilibrium) of each component in the solution represents a binary phase...
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Bonding in Metals02:32

Bonding in Metals

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Metallic bonds are formed between two metal atoms. A simplified model to describe metallic bonding has been developed by Paul Drüde called the “Electron Sea Model”. 
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Alkali Metals03:06

Alkali Metals

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Group 1 elements are soft and shiny metallic solids. They are malleable, ductile, and good conductors of heat and electricity. The melting points of the alkali metals are unusually low for metals and decrease going down the group, while the density increases going down the group with the exception of potassium (Table 1).
Table 1: Properties of the alkali metals
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Video Experimental Relacionado

Updated: Jan 22, 2026

Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers
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Author Spotlight: Experimental Approaches for the Synthesis of Low-Valent Metal-Organic Frameworks from Multitopic Phosphine Linkers

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Ajuste de la expansión térmica en estructuras metálicas orgánicas utilizando un enfoque de solución sólida de enlace

Samuel J Baxter1, Andreas Schneemann1, Austin D Ready1

  • 1Sandia National Laboratory , Livermore , California 94550 , United States.

Journal of the American Chemical Society
|July 20, 2019
PubMed
Resumen

Los investigadores lograron ajustar continuamente la expansión térmica negativa a positiva en marcos orgánicos metálicos (MOF) mediante la creación de soluciones sólidas. Este avance ofrece un nuevo control sobre las propiedades térmicas de MOF.

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Área de la Ciencia:

  • Ciencias de los materiales
  • Química
  • Física del estado sólido

Sus antecedentes:

  • Se sabe que las estructuras metal-orgánicas (MOF) exhiben expansión térmica negativa (NTE).
  • El ajuste continuo de la expansión térmica de negativo a positivo en una sola fase MOF no se ha informado previamente.
  • Los materiales NTE tradicionales carecen de esta característica ajustable.

Objetivo del estudio:

  • Investigar el ajuste continuo de la expansión térmica en un sistema MOF.
  • Explorar la formación de soluciones sólidas monofásicas para el control de la expansión térmica.
  • Establecer una estrategia general para adaptar la expansión térmica en los MOF.

Principales métodos:

  • Síntesis de una serie de soluciones sólidas de enlace mezcladas en el sistema Zn-DMOF-TM.
  • Caracterización de las propiedades de expansión térmica de los MOF sintetizados.
  • Análisis de los cambios estructurales que influyen en el comportamiento de expansión térmica.

Principales resultados:

  • Se observó una transición suave de la expansión térmica negativa a positiva en el plano a-b del material tetragonal.
  • La temperatura de expansión térmica cero cambió de ~ 186 K a ~ 325 K con el aumento del contenido de TM-bdc.
  • La formación exitosa de soluciones sólidas monofásicas permitió el ajuste continuo de la expansión térmica.

Conclusiones:

  • Las soluciones sólidas de enlace mixto representan una estrategia viable y general para controlar la expansión térmica en los MOF.
  • Este trabajo demuestra una adaptabilidad sin precedentes de la expansión térmica en un solo sistema MOF.
  • Los hallazgos allanan el camino para el diseño de MOF con características específicas de expansión térmica.