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Hydrogenation06:06

Hydrogenation

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Source: Vy M. Dong and Zhiwei Chen, Department of Chemistry, University of California, Irvine, CA
This experiment will demonstrate the hydrogenation of chalcone as an example of an alkene hydrogenation reaction (Figure 1). In this experiment, palladium on carbon (Pd/C) will be used as a heterogeneous catalyst for the process. A balloon will be used to supply the hydrogen atmosphere.
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Synthesis of an Oxygen-Carrying Cobalt(II) Complex11:46

Synthesis of an Oxygen-Carrying Cobalt(II) Complex

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Source: Deepika Das, Tamara M. Powers, Department of Chemistry, Texas A&M University
Bioinorganic chemistry is the field of study that investigates the role that metals play in biology. Approximately half of all proteins contain metals and it is estimated that up to one third of all proteins rely on metal-containing active sites to function. Proteins that feature metals, called metalloproteins, play a vital role in a variety of cell functions that are necessary for life. Metalloproteins...
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Experimental Methods for Efficient Solar Hydrogen Production in Microgravity Environment11:38

Experimental Methods for Efficient Solar Hydrogen Production in Microgravity Environment

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Efficient solar-hydrogen production has recently been realized on functionalized semiconductor-electrocatalyst systems in a photoelectrochemical half-cell in microgravity environment at the Bremen Drop Tower. Here, we report the experimental procedures for manufacturing the semiconductor-electrocatalyst device, details of the experimental set-up in the drop capsule and the experimental sequence during free...
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Hydrogen Bonds00:26

Hydrogen Bonds

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Hydrogen bonds are weak attractions between atoms that have formed other chemical bonds. One of these atoms is electronegative, like oxygen, and has a partial negative charge. The other is a hydrogen atom that has bonded with another electronegative atom and has a partial positive charge.
Hydrogen Bonds Control the World!
Because hydrogen has very weak electronegativity when it binds with a strongly electronegative atom, such as oxygen or nitrogen, electrons in the bond are unequally shared....
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Hydrogen Bonds01:04

Hydrogen Bonds

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A hydrogen bond is formed when a weakly positive hydrogen atom already bonded to one electronegative atom (for example, the oxygen in the water molecule) is attracted to another electronegative atom from another polar molecule, such as water (H2O), hydrogen fluoride (HF), or ammonia (NH3). The huge electronegativity difference between the H atom (2.1) and the atom to which it is bonded (4.0 for an F atom, 3.5 for an O atom, or 3.0 for an N atom), combined with the very small size of an H atom...
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Preparation of SNS Cobalt(II) Pincer Model Complexes of Liver Alcohol Dehydrogenase06:31

Preparation of SNS Cobalt(II) Pincer Model Complexes of Liver Alcohol Dehydrogenase

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The preparation of SNS pincer cobalt(II) model complexes of liver alcohol dehydrogenase is presented here. The complexes can be prepared by reacting the ligand precursor with CoCl2·6H2O and can then be recrystallized by allowing diethyl ether to slowly diffuse into an acetonitrile solution that contains the cobalt...
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Updated: Jan 20, 2026

Catalytic Hydrogenation of Alkene: Applications in Chemistry
06:06

Catalytic Hydrogenation of Alkene: Applications in Chemistry

Published on: April 30, 2023

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Hidrógeno en fosfuro de cobalto

Murielle F Delley1, Zishan Wu1, M Elizabeth Mundy2

  • 1Department of Chemistry , Yale University , New Haven , Connecticut 06520-8107 , United States.

Journal of the American Chemical Society
|September 4, 2019
PubMed
Resumen
Este resumen es generado por máquina.

El fosfuro de cobalto (CoP) se une efectivamente a cantidades significativas de hidrógeno reactivo, crucial para su papel como catalizador abundante en la tierra en la reacción de evolución del hidrógeno (HER). Este estudio cuantifica la estequiometría y la termoquímica del hidrógeno en las superficies de CoP.

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Área de la Ciencia:

  • Ciencias de los materiales
  • Catálisis
  • La electroquímica

Sus antecedentes:

  • El fosfuro de cobalto (CoP) es un prometedor catalizador abundante en la tierra para la reacción de evolución del hidrógeno (HER).
  • Comprender la unión de hidrógeno en las superficies del catalizador es fundamental para optimizar la eficiencia de HER.
  • Los datos experimentales sobre la energía de unión del hidrógeno para los fosfuros de metales de transición son escasos.

Objetivo del estudio:

  • Medir experimentalmente la estequiometría y la termoquímica del hidrógeno unido al fosfuro de cobalto (CoP).
  • Investigar la presencia y la reactividad del hidrógeno tanto en la CoP mesoscala como en la nanopartícula.
  • Proporcionar una nueva perspectiva sobre las propiedades catalíticas del CoP basadas en sus características de unión al hidrógeno.

Principales métodos:

  • Cuantificación del hidrógeno enlazado mediante hidrogenación alquina y reacciones de transferencia de átomos de H.
  • Estimación de las energías libres de unión de hidrógeno mediante estudios de reactividad con diversos reactivos.
  • Espectroscopia de absorción de rayos X operando para sondear los cambios estructurales en el COP hidrogenado.

Principales resultados:

  • El tratamiento con H2 introdujo sustancialmente hidrógeno reactivo en la CoP (aprox. 0.2 H por unidad de CoP).
  • Las energías libres estimadas de enlace para los átomos de H en CoP oscilan entre 51 y 66 kcal mol-1.
  • Operando XAS se indicó la expansión de la celosía y ningún cambio significativo en la carga nuclear coefectiva tras la hidrogenación.

Conclusiones:

  • Las superficies de CoP albergan una cantidad significativa de hidrógeno reactivo, lo que afecta su rendimiento catalítico y electrocatalítico.
  • El enfoque experimental proporciona un método para estudiar la unión de hidrógeno con otros materiales.
  • Estos hallazgos ofrecen información fundamental sobre el mecanismo de la CoP en el HER y las reacciones relacionadas.