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Limiting Reactant02:27

Limiting Reactant

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The relative amounts of reactants and products represented in a balanced chemical equation are often referred to as stoichiometric amounts. However, in reality, the reactants are not always present in the stoichiometric amounts indicated by the balanced equation.
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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Combustion Energy: A Measure of Stability in Alkanes and Cycloalkanes02:14

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The low reactivity in alkanes can be attributed to the non-polar nature of C–C and C–H σ bonds. Alkanes, therefore, were  initially termed as “paraffins,” derived from the Latin words: parum, meaning “too little,” and affinis, meaning “affinity.”
Alkanes undergo combustion in the presence of excess oxygen and high-temperature conditions to give carbon dioxide and water. A combustion reaction is the energy source in natural gas, liquified...
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Turnover Number and Catalytic Efficiency01:19

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The turnover number of an enzyme is the maximum number of substrate molecules it can transform per unit time. Turnover numbers for most enzymes range from 1 to 1000 molecules per second. Catalase has the known highest turnover number, capable of converting up to 2.8×106 molecules of hydrogen peroxide into water and oxygen per second. Lysozyme has the lowest known turnover number of half a molecule per second.
Chymotrypsin is a pancreatic enzyme that breaks down proteins during digestion....
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Internal Combustion Engine01:20

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The internal combustion engine is a heat engine that uses the byproducts of combustion as the working fluid instead of using a heat transfer medium to transfer heat. The combustion is done in a way that produces high-pressure combustion products that can be expanded through a turbine or piston to create work. Internal combustion engines can again be categorized into three kinds: (1) spark ignition gasoline engines, most commonly used in automobiles, (2) compression ignition diesel engines that...
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Bioreactor Controls-II01:18

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In aerobic fermentations, oxygen is vital for microbial growth and metabolite production. Since air comprises only about 20% oxygen and the gas is poorly soluble in water—just 9 ppm at 20°C—supplying sufficient oxygen becomes a critical challenge, especially in high-demand processes like yeast growth or citric acid production. Even a fully saturated broth may offer only a few seconds of oxygen availability.To address this, sterile or scrubbed air is introduced into the...
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Updated: May 4, 2026

Fabricating Degradable Thermoresponsive Hydrogels on Multiple Length Scales via Reactive Extrusion, Microfluidics, Self-assembly, and Electrospinning
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Reprogramación de las propiedades del hidrogel utilizando un ciclo de reacción impulsado por combustible

Nishant Singh1, Bruno Lainer1, Georges J M Formon1

  • 1Université de Strasbourg, CNRS, ISIS, 8 allée Gaspard Monge, 67000 Strasbourg, France.

Journal of the American Chemical Society
|February 18, 2020
PubMed
Resumen
Este resumen es generado por máquina.

Este estudio introduce un sistema catalítico artificial que controla el montaje y desmontaje del hidrogel utilizando un combustible químico. La velocidad de generación de combustible dicta las propiedades del material, lo que permite la reprogramación programable del hidrogel.

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Área de la Ciencia:

  • Química supramolecular
  • Ciencias de los materiales
  • La cinética química

Sus antecedentes:

  • La naturaleza emplea la catálisis en procesos de no equilibrio como el montaje / desmontaje de la actina y la tubulina.
  • Las reacciones enzimáticas como la oxidación de la metionina y la hidrólisis del trifosfato de guanosina son ejemplos clave.

Objetivo del estudio:

  • Presentar un ciclo de reacción artificial para el control del montaje y desmontaje del hidrogel.
  • Demostrar cómo la generación de combustible catalítico influye en las propiedades y cinética de los materiales.

Principales métodos:

  • Desarrollo de un ciclo de reacción artificial impulsado por combustible generado catalíticamente a partir de un pre-combustible.
  • Utilizando el ciclo de reacción para controlar el desmontaje y reensamblaje de un hidrogel.
  • Investigar el impacto de la tasa de rotación previa al combustible en la morfología y las propiedades mecánicas del hidrogel.

Principales resultados:

  • El ciclo de reacción artificial controló con éxito la dinámica del hidrogel.
  • Se demostró que la tasa de rotación previa al combustible dicta la morfología y las características mecánicas del hidrogel.
  • Los hidrogeles fueron reprogramados repetidamente mediante la adición de combustible fresco y la eliminación de residuos.

Conclusiones:

  • La generación de combustible catalítico ofrece un método para controlar la cinética de reacción/ensamblaje en sistemas artificiales.
  • Este enfoque permite el control dinámico de las propiedades de los materiales en sistemas supramoleculares no equilibrados.
  • Los hallazgos proporcionan información sobre la creación de materiales reales y sensibles.