Región invertida en la transferencia de electrones bimolecular en la solución habilitada por la deslocalización

Norihiko Takeda1, John R Miller1

  • 1Chemistry Division, Brookhaven National Laboratory, Upton, New York 11937, United States.

PubMed
Resumen

Las constantes de velocidad de transferencia de electrones muestran una región invertida, explicada por la teoría e influenciada por el tamaño del donante. Los acoplamientos electrónicos más pequeños en sistemas deslocalizados permiten esta región invertida de Marcus, crucial para la eficiencia del almacenamiento de energía.

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