Video Experimental Relacionado

Updated: Nov 24, 2025

Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex
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Line Shape Analysis of Dynamic NMR Spectra for Characterizing Coordination Sphere Rearrangements at a Chiral Rhenium Polyhydride Complex

Published on: July 27, 2022

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Los complejos de rodio en la formación de enlaces P-C: papel clave de un ligando hidrido

Víctor Varela-Izquierdo1, Ana M Geer1, Janeth Navarro1

  • 1Departamento de Química Inorgánica, Instituto de Síntesis Química y Catálisis Homogénea (ISQCH), CSIC-Universidad de Zaragoza, Pedro Cerbuna 12, 50009 Zaragoza, Spain.

Journal of the American Chemical Society
|December 28, 2020
PubMed
Resumen

Este estudio revela que un catalizador de rodio, [Rh ((Tp) H ((PMe3) ((PPh2) ], promueve eficazmente la hidrofosfación de las olefinas. El ligando hidruro juega un papel crucial en la facilitación de la formación de enlaces P-C y H-C para la síntesis de fosfanos funcionalizados.

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