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Network Covalent Solids02:18

Network Covalent Solids

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Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
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Ionic Crystal Structures02:42

Ionic Crystal Structures

16.0K
Ionic crystals consist of two or more different kinds of ions that usually have different sizes. The packing of these ions into a crystal structure is more complex than the packing of metal atoms that are the same size.
Most monatomic ions behave as charged spheres, and their attraction for ions of opposite charge is the same in every direction. Consequently, stable structures for ionic compounds result (1) when ions of one charge are surrounded by as many ions as possible of the opposite...
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Metallic Solids02:37

Metallic Solids

19.8K
Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
19.8K
Intermolecular Forces in Solutions02:28

Intermolecular Forces in Solutions

36.6K
The formation of a solution is an example of a spontaneous process, a process that occurs under specified conditions without energy from some external source.
When the strengths of the intermolecular forces of attraction between solute and solvent species in a solution are no different than those present in the separated components, the solution is formed with no accompanying energy change. Such a solution is called an ideal solution. A mixture of ideal gases (or gases such as helium and argon,...
36.6K
Molecular and Ionic Solids02:54

Molecular and Ionic Solids

18.9K
Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
18.9K
Lewis Structures of Molecular Compounds and Polyatomic Ions02:54

Lewis Structures of Molecular Compounds and Polyatomic Ions

41.4K
To draw Lewis structures for complicated molecules and molecular ions, it is helpful to follow a step-by-step procedure as outlined:
41.4K

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Video Experimental Relacionado

Updated: Nov 7, 2025

Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface
08:42

Microfluidic-based Synthesis of Covalent Organic Frameworks COFs: A Tool for Continuous Production of COF Fibers and Direct Printing on a Surface

Published on: July 10, 2017

13.7K

Soluciones sólidas de marco orgánico covalente bidimensional

Rebecca L Li1, Anna Yang1, Nathan C Flanders1

  • 1Department of Chemistry, Northwestern University, 2145 Sheridan Road, Evanston, Illinois 60208 United States.

Journal of the American Chemical Society
|April 28, 2021
PubMed
Resumen
Este resumen es generado por máquina.

Los investigadores crearon nuevos marcos orgánicos covalentes (COF) utilizando mezclas de monómeros. Este avance permite el ajuste continuo de las propiedades de COF, como el tamaño de los poros, ajustando las proporciones de monómeros en soluciones sólidas.

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Área de la Ciencia:

  • Ciencias de los materiales
  • Química de los polímeros
  • Nanotecnología

Sus antecedentes:

  • Las estructuras orgánicas covalentes (COF) suelen utilizar monómeros limitados para estructuras de alta simetría.
  • La síntesis de COF con múltiples monómeros a menudo conduce a una distribución estadística o a una menor simetría.

Objetivo del estudio:

  • Demostrar la formación de soluciones sólidas de COF de una sola fase a partir de mezclas de monómeros de diferentes longitudes.
  • Explorar una nueva estrategia para el diseño de COF complejos con propiedades sintonizables.

Principales métodos:

  • Polimerización de mezclas de monómeros con proporciones de alimentación variables.
  • Caracterización mediante difracción de rayos X, espectroscopia infrarroja de la transformada de Fourier y refinamiento de Pawley.

Principales resultados:

  • Formación de soluciones sólidas hexagonales de COF 2D de una sola fase con parámetros de celosía continuamente variables.
  • Distribución aleatoria de monómeros dentro de la misma celosía, confirmada por difracción y espectroscopia.
  • Pruebas de doblamiento de enlaces que acomodan monómeros de diferentes longitudes, indicadas por cambios en los parámetros de la red no lineal.

Conclusiones:

  • La formación de soluciones sólidas ofrece una nueva vía para diseñar COFs 2D con mayor complejidad.
  • La composición de monómeros sintonizables permite un control continuo de las propiedades del COF, como el tamaño promedio de los poros.
  • La polimerización directa de las mezclas es eficaz, mientras que el intercambio de enlaces post-sintéticos no es adecuado para la formación de soluciones sólidas.