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Updated: Sep 27, 2025

Isolating Free Carbenes, their Mixed Dimers and Organic Radicals
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Isomerismo de carbazoles en cationes radicales helicoidales: deslocalización del espín y inversión del nivel

Sitthichok Kasemthaveechok1, Laura Abella2, Marion Jean3

  • 1Univ Rennes, CNRS, ISCR - UMR 6226, F-35000 Rennes, France.

Journal of the American Chemical Society
|April 12, 2022
PubMed
Resumen

Desarrollamos moléculas de radicales orgánicos quirales estables utilizando sistemas conjugados π hélicos. Estas nuevas moléculas exhiben una inversión única de signos de dicroísmo electrónico circular y acoplamiento antiferromagnético, que ofrecen nuevos conocimientos sobre la energética orbital radical.

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