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Redox Equilibria: Overview01:23

Redox Equilibria: Overview

607
A reduction-oxidation reaction is commonly called a redox reaction. In a redox reaction, electrons are transferred from one species to another rather than being shared between or among atoms. The reducing agent or reductant is the species that loses electrons and gets oxidized in the process. The species that gains electrons and gets reduced in the process is the oxidizing agent or oxidant. Redox reactions are represented as two separate equations called half-reactions, where one equation...
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Redox Reactions01:24

Redox Reactions

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Oxidation-reduction or redox reactions involve the transfer of electrons from one molecule or atom to another. When an atom gains an electron, another atom must lose an electron, meaning oxidation and reduction must occur together. Since the redox occurs in pairs, the atom that gets oxidized is also called the reducing agent or reductant, and the atom that is reduced is also called the oxidizing agent or oxidant. A straightforward way to remember the definitions of oxidation and reduction is...
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Redox Titration: Other Oxidizing and Reducing Agents01:26

Redox Titration: Other Oxidizing and Reducing Agents

361
Besides iodine, other oxidizing or reducing agents can serve as titrants in redox titrations. Common oxidizing titrants include KMnO4, cerium(IV), and K2Cr2O7. The choice of oxidizing titrants depends on factors like stability, cost, analyte strength, and reaction rate between the analyte and titrant. KMnO4 is a strong oxidizing titrant that reduces from Mn(VII) to Mn(II) in a highly acidic solution, simultaneously oxidizing the analyte to a higher oxidation state. In this case, KMnO4 acts as a...
361
Balancing Redox Equations02:58

Balancing Redox Equations

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Electrochemistry is the science involved in the interconversion of electrical and chemical reactions. Such reactions are called reduction-oxidation, or redox reactions. These important reactions are defined by changes in oxidation states for one or more reactant elements and include a subset of reactions involving the transfer of electrons between reactant species. Electrochemistry as a field has evolved to yield sufficient insights on the fundamental principles of redox chemistry and multiple...
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Oxidation-Reduction Reactions03:11

Oxidation-Reduction Reactions

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Oxidation–Reduction Reactions
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Oxidation and Reduction of Organic Molecules01:19

Oxidation and Reduction of Organic Molecules

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Energy production within a cell involves many coordinated chemical pathways. Most of these pathways are combinations of oxidation and reduction reactions, which occur at the same time. An oxidation reaction strips an electron from an atom in a compound, and the addition of this electron to another compound is a reduction reaction. Because oxidation and reduction usually occur together, these pairs of reactions are called redox reactions.
The removal of an electron from a molecule, results in a...
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Updated: Aug 14, 2025

Simple Methods for the Preparation of Non-noble Metal Bulk-electrodes for Electrocatalytic Applications
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Simple Methods for the Preparation of Non-noble Metal Bulk-electrodes for Electrocatalytic Applications

Published on: June 21, 2017

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Mediadores redox en la coelectrocatálisis homogénea

Amelia G Reid1, Charles W Machan1

  • 1Department of Chemistry, University of Virginia, P.O. Box 400319, Charlottesville, Virginia 22904-4319, United States.

Journal of the American Chemical Society
|January 18, 2023
PubMed
Resumen

La coelectrocatálisis homogénea utiliza mediadores redox (RM) para mejorar el rendimiento del catalizador para la producción de energía verde y química. Esta estrategia es prometedora, pero requiere una mayor investigación fundamental para una aplicación industrial más amplia.

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Área de la Ciencia:

  • Catálisis
  • Química ecológica
  • La electrocatálisis

Sus antecedentes:

  • La electrocatálisis homogénea es crucial para convertir pequeñas moléculas en productos valiosos para la energía verde y las materias primas químicas.
  • La aplicación industrial de estos sistemas requiere una mayor actividad y estabilidad de los catalizadores.
  • Las enzimas utilizan mediadores redox (RM) para entregar equivalentes redox a los sitios activos.

Objetivo del estudio:

  • Para resumir los avances recientes en la electrocatálisis homogénea.
  • Discutir el potencial del uso de mediadores redox (RM) en sistemas electrocatalíticos.
  • Identificar las direcciones futuras de la investigación en este campo en desarrollo.

Principales métodos:

  • Revisión de la literatura reciente sobre la electrocatálisis homogénea.
  • Análisis de sistemas que emplean catalizadores homogéneos y mediadores redox.
  • Discusión del ámbito de aplicación de los sustratos, incluidos los alcoholes, el nitrógeno, los sustratos orgánicos insaturados, el oxígeno y el dióxido de carbono.

Principales resultados:

  • Se han desarrollado sistemas coelectrocatalíticos con catalizadores homogéneos y RM para diversas conversiones de sustratos.
  • Los mediadores redox (RM) pueden aumentar la actividad del catalizador y mejorar la selectividad del producto.
  • Estos sistemas pueden alterar los ciclos catalíticos y evitar los intermedios de alta energía.

Conclusiones:

  • La coelectrocatálisis homogénea es una estrategia prometedora para mejorar los procesos electrocatalíticos.
  • Se necesitan más avances fundamentales para establecerlo como una estrategia industrial general.
  • El campo ofrece un potencial significativo para el desarrollo futuro de la química sostenible.