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Updated: Jul 22, 2025

Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides
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Efficient Synthesis of All-Carbon Quaternary Centers via the Conjugate Addition of Functionalized Monoorganozinc Bromides

Published on: May 26, 2019

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Los catalizadores quirales iónicos derivados de aminoácidos permiten desimetrizar el acoplamiento cruzado a los

Junqiang Wei1, Vincent Gandon2, Ye Zhu1

  • 1Department of Chemistry, Faculty of Science, National University of Singapore, 3 Science Drive 3, Singapore 117543, Singapore.

Journal of the American Chemical Society
|July 20, 2023
PubMed
Resumen

Este estudio introduce nuevos catalizadores quirales iónicos para la desimetrización remota, lo que permite la creación de moléculas quirales complejas a través de reacciones de acoplamiento cruzado enantioselectivas. Estos catalizadores logran un preciso control estéreo de largo alcance aprovechando la dirección electrostática y las interacciones cooperativas.

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