Jove
Visualize
Contáctanos

Videos de Conceptos Relacionados

Characteristics and Nomenclature of Copolymers01:24

Characteristics and Nomenclature of Copolymers

2.6K
Copolymers are the products obtained from the polymerization of multiple monomer species. So, in a polymer chain itself, there can be multiple repeating units that come from different monomers. The process of synthesizing a polymer from different monomer species is called copolymerization. When two monomers are involved, the polymer is known as a bipolymer. Polymers with three and four monomers are termed terpolymers and quaterpolymers, respectively. Figure 1 depicts the copolymerization of...
2.6K
Polymers02:34

Polymers

35.8K
The word polymer is derived from the Greek words “poly” which means “many” and “mer” which means “parts”. Polymers are long chains of molecules composed of repeating units of smaller molecules, known as monomers. They either occur naturally, such as DNA and proteins, or can be constructed synthetically, like plastics. They have varied structural characteristics, such as linear chains, branched chains, or complex networks, that contribute to the...
35.8K
Step-Growth Polymerization: Overview01:03

Step-Growth Polymerization: Overview

3.5K
Step-growth or condensation polymerization is a stepwise reaction of bi or multifunctional monomers to form long-chain polymers. As all the monomers are reactive, most of the monomers are consumed at the early stages of the reaction to form small chains of reactive oligomers, which then combine to form long polymer chains in the late stages. Hence, the reaction has to proceed for a long time to achieve high molecular weight polymers.
Many natural and synthetic polymers are produced by...
3.5K
Dehydration Synthesis01:15

Dehydration Synthesis

133.5K
Overview
Dehydration synthesis (also called a condensation reaction) is the chemical process in which two molecules covalently link together to form a new molecule, along with the release of a water molecule. Many physiologically important compounds form by dehydration synthesis reactions, such as complex carbohydrates, proteins, DNA, and RNA.
Synthesis of carbohydrates
Sugar molecules are covalently linked together by dehydration synthesis. During the reaction, the hydroxyl (-OH) group from...
133.5K
Characteristics and Nomenclature of Homopolymers01:00

Characteristics and Nomenclature of Homopolymers

3.1K
Polymers that are made up of identical monomer units are called homopolymers. Only one repeating unit is involved in the construction of the homopolymer structure. For example, as depicted in Figure 1, polypropylene is a homopolymer constituted of propylene monomers. Here, the only repeating unit in the polymer chain is propylene.
3.1K
ATP and Macromolecule Synthesis01:28

ATP and Macromolecule Synthesis

5.6K
Biological macromolecules are organic compounds, predominantly composed of carbon atoms. The carbon atoms are covalently bonded with hydrogen, oxygen, nitrogen, and other minor elements. There are four major biological macromolecule classes: carbohydrates, lipids, proteins, and nucleic acids.
Most macromolecules are composed of single subunits, or building blocks, called monomers. The monomers combine with each other using covalent bonds to form larger molecules known as polymers.
Conversion of...
5.6K

También podría leer

Artículos Relacionados

Artículos vinculados a este trabajo por autores compartidos, revista y gráfico de citas.

Ordenar por
Same author

Sequential Single-Crystal-to-Single-Crystal Transformations Generate Polymer Polymorphs.

Angewandte Chemie (International ed. in English)·2026
Same author

DNA-interacting lanthanide complexes with a DOTA-derived dipyrido[3,2-<i>a</i>;2',3'-<i>c</i>]phenazine ligand for near-infrared luminescence.

Dalton transactions (Cambridge, England : 2003)·2026
Same author

Salt Formation as a Regioselectivity Tuning Strategy in Topochemical Polymerization: Generating Two Structurally Distinct Polymers from One Monomer.

Journal of the American Chemical Society·2026
Same author

Orthogonal Topochemical Reactions in a Single Crystal Mediated by Distinct Physical Stimuli.

Angewandte Chemie (International ed. in English)·2026
Same author

A hydroxyl group dictates handedness, pitch, and mechanics in a crystalline covalent helical polymer.

Science advances·2025
Same author

Topochemical Synthesis of a Syndiotactic Polymer from a Racemic Monomer.

Journal of the American Chemical Society·2025
Same journal

Gas-Responsive Metal-Organic Frameworks for Adaptive Thermal Energy Storage with Tunable Charge-Discharge Temperatures.

Journal of the American Chemical Society·2026
Same journal

Engineering a Thiamine-Dependent Benzoylformate Decarboxylase for Stereodivergent Radical C(sp<sup>3</sup>)-C(sp<sup>3</sup>) Bond Formation.

Journal of the American Chemical Society·2026
Same journal

Accelerated Directional Proton-Coupled Electron Transfer Enabled by Intrinsic Dipole Field in Biomimetic α-Helical Structure.

Journal of the American Chemical Society·2026
Same journal

Alternating Current-Driven Hydrogen Isotope Labeling of Aliphatic Amines Using 1,3-Propanedithiol as an Efficient Hydrogen Atom Transfer Reagent.

Journal of the American Chemical Society·2026
Same journal

Two-Dimensional van der Waals Polar Metal MoOBr<sub>2</sub>.

Journal of the American Chemical Society·2026
Same journal

Negatively Curved Chiral Bilayer Nanographene.

Journal of the American Chemical Society·2026
Ver todos los artículos relacionados
JoVE
x logofacebook logolinkedin logoyoutube logo
ACERCA DE JoVE
Visión GeneralLiderazgoBlogCentro de Ayuda JoVE
AUTORES
Proceso de PublicaciónConsejo EditorialAlcance y PolíticasRevisión por ParesPreguntas FrecuentesEnviar
BIBLIOTECARIOS
TestimoniosSuscripcionesAccesoRecursosConsejo Asesor de BibliotecasPreguntas Frecuentes
INVESTIGACIÓN
JoVE JournalMethods CollectionsJoVE Encyclopedia of ExperimentsArchivo
EDUCACIÓN
JoVE CoreJoVE BusinessJoVE Science EducationJoVE Lab ManualCentro de Recursos para ProfesoresSitio de Profesores
Términos y Condiciones de Uso
Política de Privacidad
Políticas

Video Experimental Relacionado

Updated: Jul 15, 2025

Using Polystyrene-block-polyacrylic acid-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization
09:02

Using Polystyrene-block-polyacrylic acid-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization

Published on: July 9, 2015

12.3K

Dos polímeros estructuralmente diferentes de un solo monómero

Javed R Pathan1, Subhrajyoti Bhandary1, Kana M Sureshan1

  • 1School of Chemistry, Indian Institute of Science Education and Research Thiruvananthapuram, Vithura, Thiruvananthapuram 695551, India.

Journal of the American Chemical Society
|October 3, 2023
PubMed
Resumen
Este resumen es generado por máquina.

Los investigadores sintetizaron un nuevo monómero de malonamida para la polimerización topoquímica, obteniendo dos polímeros distintos similares al nylon con diferentes estructuras y topologías a través de la cicloadición azida-alquina. Este trabajo innovador permite un control preciso de la arquitectura del polímero.

Más Videos Relacionados

Synthesis of Monodisperse Cylindrical Nanoparticles via Crystallization-driven Self-assembly of Biodegradable Block Copolymers
11:42

Synthesis of Monodisperse Cylindrical Nanoparticles via Crystallization-driven Self-assembly of Biodegradable Block Copolymers

Published on: June 20, 2019

7.9K
Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
08:12

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers

Published on: December 16, 2022

3.3K

Videos de Experimentos Relacionados

Last Updated: Jul 15, 2025

Using Polystyrene-block-polyacrylic acid-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization
09:02

Using Polystyrene-block-polyacrylic acid-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization

Published on: July 9, 2015

12.3K
Synthesis of Monodisperse Cylindrical Nanoparticles via Crystallization-driven Self-assembly of Biodegradable Block Copolymers
11:42

Synthesis of Monodisperse Cylindrical Nanoparticles via Crystallization-driven Self-assembly of Biodegradable Block Copolymers

Published on: June 20, 2019

7.9K
Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
08:12

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers

Published on: December 16, 2022

3.3K

Área de la Ciencia:

  • Química de los polímeros
  • Ciencias de los materiales
  • La cristalografía

Sus antecedentes:

  • La polimerización topoquímica ofrece una ruta a los polímeros cristalinos con estructuras controladas.
  • La cicloadición azida-alquina es una reacción química de clic versátil para la síntesis de polímeros.

Objetivo del estudio:

  • Diseñar y sintetizar un monómero derivado de la malonamida para la polimerización topoquímica.
  • Investigar la formación de dos estructuras poliméricas distintas a partir de un solo monómero.
  • Para aclarar los detalles a nivel atómico del proceso de polimerización y las topologías de polímeros resultantes.

Principales métodos:

  • Síntesis de un monómero de malonamida con funcionalidades de azida y alquina.
  • Cristalización para obtener dos polimorfos (M1 y M2).
  • Difracción de rayos X de un solo cristal para analizar las estructuras cristalinas y las vías de polimerización.
  • Análisis térmico para inducir la polimerización topoquímica.

Principales resultados:

  • Se obtuvieron dos polimorfos concomitantes (M1 y M2) del monómero.
  • Ambos polimorfos se sometieron a una polimerización de cicloadición azida-alquina.
  • El polimorfo M1 produjo un polímero 1,4-disubstituido ligado al triazolilo, con polimerización perpendicular a los enlaces de hidrógeno.
  • El polimorfo M2 produjo un polímero 1,5-disubstituido ligado al triazolilo, con polimerización a lo largo de enlaces de hidrógeno.
  • Dos polímeros estructuralmente isoméricos con topologías distintas fueron sintetizados a través de transformaciones de un solo cristal a un solo cristal.

Conclusiones:

  • Este estudio informa de la primera síntesis topoquímica de dos polímeros estructuralmente isómeros a partir de un solo monómero.
  • El embalaje cristalino dicta la regioquímica y la topología de los polímeros resultantes.
  • La polimerización de un solo cristal a otro proporciona información de resolución atómica sobre la formación de polímeros.