Controlar el acoplamiento de intercromóforos en dímeros de pentaceno vinculados a diamantano para crear un par

Phillip M Greißel1, Zachary W Schroeder2, Dominik Thiel1

  • 1Department of Chemistry and Pharmacy & Interdisciplinary Center for Molecular Materials (ICMM), Friedrich-Alexander-Universität Erlangen-Nürnberg (FAU), Egerlandstrasse 3, 91058 Erlangen, Germany.

Resumen

Se sintetizaron dos dímeros isoméricos de pentaceno para probar cómo los espaciadores de diamante controlan el acoplamiento electrónico. El patrón de sustitución en el espaciador dicta si se produce la fisión de singletas intramolecular, lo que demuestra el control binario sobre la interacción de los cromóforos.

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