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Updated: Jun 17, 2025

Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
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Preparation of a Corannulene-functionalized Hexahelicene by CopperI-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

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Terpenoides ciclófanos con quiralidad plana

Alina Trofimova1, Matthew Diamandas1, Chelsey Brien1

  • 1Davenport Research Laboratories, Department of Chemistry, University of Toronto, Toronto M5S 3H6, Canada.

Journal of the American Chemical Society
|August 12, 2024
PubMed
Resumen

Los ciclofanos quirales sintetizados a partir de terpenos naturales como el citronelol muestran una tensión significativa en el anillo. Esta cepa influye en su estabilidad y reactividad, lo que lleva a la formación de isómeros inesperados.

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