Un mecanismo alternativo para la desaturación de C-C subraya un mecanismo de doble control para el destino de los

Xuan Zhang1,2, Lanteng Wang3, Jia Liu1

  • 1State Key Laboratory of Physical Chemistry of Solid Surfaces and Fujian Provincial Key Laboratory of Theoretical and Computational Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, P. R. China.

Resumen

Las oxigenasas dependientes de hierro (II) y 2-oxo) glutarato (Fe / 2OG) catalizan la desaturación de C-C. Este estudio revela un nuevo mecanismo intermedio de oxafosfirano, eludiendo la hidroxilación para la biosíntesis selectiva de productos naturales.

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