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Updated: Jan 8, 2026

Monolayer Contact Doping of Silicon Surfaces and Nanowires Using Organophosphorus Compounds
Published on: December 2, 2013
Estrategia de dopaje complementario para lograr baja resistencia de contacto en transistores de efecto de campo
Mayukh Das1, Krishnendu Mukhopadhyay1, Md Sajjad Alam2
1Engineering Science and Mechanics, Penn State University, University Park, Pennsylvania 16802, United States.
Abstract:
Lowering contact resistance (RC) is essential for achieving high-performance complementary logic circuits based on two-dimensional (2D) field-effect transistors (FETs). Although n-type 2D FETs have reached sub-100 Ω·μm RC, attaining a similar performance in p-type devices remains difficult due to large Schottky barriers for hole injection. We present a strategy to reduce RC in p-type monolayer WSe2 FETs to the sub-kΩ·μm range by combining complementary doping with a clean 2D/2D van der Waals (vdW) interface. Degenerately Ta-doped multilayer MoSe2 acts as a robust p-type contact and is laminated onto the MOCVD-grown WSe2 channels. A postfabrication NO anneal induces selective channel doping through NO chemisorption at Se-vacancy sites while preserving the Ta-doped MoSe2 contact properties. This combined channel and contact engineering enable efficient hole injection, yielding ION values up to 53 μA/μm. The approach narrows the performance gap between n- and p-type 2D transistors and advances the prospects for complementary 2D logic technologies.
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