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Patterning via Optical Saturable Transitions - Fabrication and Characterization
Published on: December 11, 2014
Arquitecturas fotónicas blandas pintables con actuación lumínica multiestable
Honglong Hu1,2, Wentan Wan3, Xuan Liu3
1Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Shanghai Key Laboratory of Functional Materials Chemistry, Feringa Nobel Prize Scientist Joint Research Center, Institute of Fine Chemicals, Frontiers Science Center for Materiobiology and Dynamic Chemistry, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai, 200237, China.
Abstract:
Dynamic photoprogramming of paintable liquid crystal photonic devices with multi-stability shows practical application in smart soft materials and responsive optics. However, there exist three key challenges that limit their development: achieving precise paintability with controllable viscosity and resolution, maintaining well-ordered liquid crystal photonic structures, and enabling multi-stable photoresponsive behavior. Here, we address these limitations by incorporating an intrinsic photoswitch into a cellulose-based liquid crystal system, further constructing a unique paintable helical photonic architecture featuring both multi-stability and dynamic light-actuation. The intrinsic chiral photoswitch enables multi-stable modulation of helical pitch, while optimized viscosity restrains the remarkable fluidity of traditional liquid crystal systems and matches proper surface anchoring, thereby allowing for paintability and programming of a photonic device. The cutting-edge single-step painting enables highly efficient, large-area and well-defined patterning of helical architectures on diverse flexible substrates, thereby promoting prospective applications in anti-counterfeiting, information encryption, and smart window-film. This strategy establishes a robust and versatile foundation that integrates practical explorations in soft matter photonics with state-of-the-art engineering applications, such as multifunctional interactive optical information systems and advanced intelligent flexible sensors.

