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Updated: Jan 7, 2026

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Un solo átomo de silicio anclado en una monocapa de α-BS para la reducción electrocatalítica eficiente del óxido

Yongxu Fu¹, Hu Li¹, Qingbo Kang¹

¹Key Laboratory of Brain-like Neuromorphic Devices and Systems of Hebei Province, College of Electronic and Information Engineering, Hebei University, Baoding 071002, P. R. China. wanglinxia@hbu.edu.cn.

Physical chemistry chemical physics : PCCP

|January 2, 2026

Resumen

No abstract available in PubMed .

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Nitriles are reduced to amines in the presence of strong reducing agents like lithium aluminum hydride through a typical nucleophilic acyl substitution. The reaction requires two equivalents of the reducing agent. The reducing agent acts as a source of hydride ions.
As shown below, the mechanism involves three steps. Firstly, the hydride ion acting as a nucleophile attacks the nitrile carbon to form an anion. In the second step, a second equivalent of the hydride ion attacks the anion to...