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MOS Capacitor01:25

MOS Capacitor

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A Metal-Oxide-Semiconductor (MOS) capacitor is a fundamental structure used extensively in semiconductor device technology, particularly in the fabrication of integrated circuits and MOSFETs (metal-oxide-semiconductor field-effect transistors). The MOS capacitor consists of three layers: a metal gate, a dielectric oxide, and a semiconductor substrate.
The metal gate is typically made from highly conductive materials such as aluminum or polysilicon. Beneath the metal gate lies a thin layer of...
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Design Example: Resistive Touchscreen01:14

Design Example: Resistive Touchscreen

690
A device engineer plays a crucial role in designing user interfaces for mobile devices. One such interface is the resistive touchscreen, which fundamentally consists of two metallic layers: a flexible upper layer and a rigid lower layer, separated by a narrow gap. The high resistance between these two layers is a key characteristic of this design.
When a user touches the screen, the two layers make contact at a specific point known as the touchpoint. This contact reduces the resistance between...
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Dielectric Polarization in a Capacitor01:31

Dielectric Polarization in a Capacitor

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The presence of a dielectric medium in a capacitor not only changes the voltage and capacitance but also affects the electric field. In general, dielectrics can be of two types: polar and nonpolar. In a polar dielectric, the positive and negative charges in the molecules are separated by a distance and hence have a permanent dipole moment. In contrast, no such charge separation exists in a nonpolar dielectric, however the nonpolar molecules get polarized in the presence of an external electric...
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Potentiometry: Types of Electrodes01:19

Potentiometry: Types of Electrodes

1.9K
Reference electrodes serve as a stable reference point for potentiometric measurements, while indicator and working electrodes react to variations in the composition of a solution.
The Standard Hydrogen Electrode (SHE) is a widely used reference electrode that maintains zero potential across all temperatures. However, its need for a continuous hydrogen gas supply renders it impractical for everyday use.
An alternative to SHE is the Saturated Calomel Electrode (SCE). This electrode features an...
1.9K
Potentiometry: Membrane Electrodes01:15

Potentiometry: Membrane Electrodes

1.6K
Membrane electrodes, also known as p-ion electrodes, use membranes that selectively interact with free analyte ions, generating a potential difference across the membrane. The resulting membrane potential, known as the asymmetry potential, is not zero even when analyte concentrations on both sides of the membrane are equal. The membrane's response is typically not selective to a single analyte but proportional to the concentration of all ions in the sample solution capable of interacting at...
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Standard Electrode Potentials03:02

Standard Electrode Potentials

49.8K
On comparing the reactivity of silver and lead, it is observed that the two ionic species, Ag+ (aq) and Pb2+ (aq), show a difference in their redox reactivity towards copper: the silver ion undergoes spontaneous reduction, while the lead ion does not. This relative redox activity can be easily quantified in electrochemical cells by a property called cell potential. This property is commonly known as cell voltage in electrochemistry, and it is a measure of the energy which accompanies the charge...
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Updated: Jan 13, 2026

Evaluating the Electrochemical Properties of Supercapacitors using the Three-Electrode System
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Correlaciones estructura-función en electrodos serigrafiados de grafeno: comportamiento capacitivo y de faradaico

Tharinda Kasemphong1, Monchai Jitvisate2, Chanida Jakkrawhad1

  • 1School of Chemistry, Institute of Science, Suranaree University of Technology, 111 University Avenue, Suranaree, Muang, Nakhon Ratchasima 30000, Thailand. kamonwad@g.sut.ac.th.

Physical chemistry chemical physics : PCCP
|January 6, 2026
PubMed
Resumen
Este resumen es generado por máquina.

El origen del grafeno impacta las interfaces de los electrodos serigrafiados. La química superficial, no la morfología, dicta el potencial, mientras que la capacitancia se relaciona con la humectación y la porosidad, guiando la selección de precursores para aplicaciones.

Palabras clave:
grafenoelectrodos serigrafiadoselectrocatálisiscapacitanciatransferencia de electrones

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Área de la Ciencia:

  • Electroquímica
  • Ciencia de Materiales
  • Ciencia de Superficies

Sus antecedentes:

  • La influencia del origen del grafeno en el comportamiento interfacial en electrodos serigrafiados sigue siendo poco comprendida.
  • La diversa fabricación del grafeno conduce a propiedades físicas y químicas variadas.

Objetivo del estudio:

  • Investigar cómo los diferentes orígenes del grafeno afectan las propiedades electroquímicas interfaciales de los electrodos serigrafiados.
  • Correlacionar las métricas interfaciales con las características físicas para la selección optimizada del precursor de grafeno.

Principales métodos:

  • Fabricación de cuatro tipos de electrodos serigrafiados de grafeno (comercial, derivado de combustión, exfoliado, cultivado en CVD) utilizando una tinta estandarizada y un protocolo de impresión.
  • Aplicación de electroanálisis convencional y espectroscopía electroquímica de potencial escalonado para determinar la capacitancia diferencial (C(E)) y las escalas de tiempo de carga (τ).
  • Evaluación de la cinética de transferencia de electrones heterogénea para un par redox ([Fe(CN)6]4-/3-) para sondear procesos faradaicos.

Principales resultados:

  • Todos los electrodos exhibieron potenciales de punto cero de carga (PZC) similares (0,35-0,40 V vs. Ag/AgCl), gobernados principalmente por la química superficial y la estructura electrónica.
  • La capacitancia de doble capa (Cdl) se correlacionó con la humectación del electrodo y la mesoporosidad.
  • Las escalas de tiempo de carga (τ) fueron consistentes (15-25 ms) y estuvieron influenciadas por el equilibrio entre la resistencia de acceso iónico y la capacitancia.
  • Las tasas de transferencia de electrones heterogénea (k0) dependieron de las funcionalidades de borde, defecto y oxígeno, en lugar de la conductividad de la película, con valores que oscilan entre (0,76-1,99) × 10^-5 m s^-1.

Conclusiones:

  • Las propiedades electroquímicas interfaciales (capacitivas y faradaicas) de los electrodos serigrafiados de grafeno están directamente relacionadas con características físicas como la porosidad, la densidad de defectos y la química superficial.
  • Estos hallazgos ofrecen criterios iniciales para seleccionar precursores de grafeno apropiados en función de las características interfaciales deseadas para aplicaciones en detección, catálisis y almacenamiento de energía.