Ingeniería de Puntos Cuánticos de Carbono y Nitrógeno mediante Dopaje con Azufre para la Generación Controlada de...

Carbon nitride quantum dots (CNQDs) are emerging as versatile photocatalytic materials with promising applications in biomedicine and environmental remediation. In this study, we synthesized pristine and sulfur-doped CNQDs via a hydrothermal method, and characterized them using transmission electron microscopy (TEM), X-ray photoelectron spectroscopy (XPS), and UV-vis absorption spectroscopy. For the first time, the quantum yields of superoxide and singlet oxygen generation were measured for CNQDs. Sulfur doping was found to significantly enhance superoxide generation while concurrently suppressing singlet oxygen production, offering a powerful mechanism for tailoring reactive oxygen species (ROS) output. In addition, all CNQD samples produced hydrogen peroxide and hydroxyl radicals. The ability of these nanomaterials to produce multiple ROS types underscores their potential as hypoxia-resistant photosensitizers (PSs) for photodynamic therapy (PDT) and as efficient photocatalysts for pollutant degradation.