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Batteries and Fuel Cells03:12

Batteries and Fuel Cells

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A battery is a galvanic cell that is used as a source of electrical power for specific applications. Modern batteries exist in a multitude of forms to accommodate various applications, from tiny button batteries such as those that power wristwatches to the very large batteries used to supply backup energy to municipal power grids. Some batteries are designed for single-use applications and cannot be recharged (primary cells), while others are based on conveniently reversible cell reactions that...
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Network Covalent Solids02:18

Network Covalent Solids

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Network covalent solids contain a three-dimensional network of covalently bonded atoms as found in the crystal structures of nonmetals like diamond, graphite, silicon, and some covalent compounds, such as silicon dioxide (sand) and silicon carbide (carborundum, the abrasive on sandpaper). Many minerals have networks of covalent bonds.
To break or to melt a covalent network solid, covalent bonds must be broken. Because covalent bonds are relatively strong, covalent network solids are typically...
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Metallic Solids02:37

Metallic Solids

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Metallic solids such as crystals of copper, aluminum, and iron are formed by metal atoms. The structure of metallic crystals is often described as a uniform distribution of atomic nuclei within a “sea” of delocalized electrons. The atoms within such a metallic solid are held together by a unique force known as metallic bonding that gives rise to many useful and varied bulk properties.
All metallic solids exhibit high thermal and electrical conductivity, metallic luster, and malleability....
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Structures of Solids02:22

Structures of Solids

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Solids in which the atoms, ions, or molecules are arranged in a definite repeating pattern are known as crystalline solids. Metals and ionic compounds typically form ordered, crystalline solids. A crystalline solid has a precise melting temperature because each atom or molecule of the same type is held in place with the same forces or energy. Amorphous solids or non-crystalline solids (or, sometimes, glasses) which lack an ordered internal structure and are randomly arranged. Substances that...
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Molecular and Ionic Solids02:54

Molecular and Ionic Solids

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Crystalline solids are divided into four types: molecular, ionic, metallic, and covalent network based on the type of constituent units and their interparticle interactions.
Molecular Solids
Molecular crystalline solids, such as ice, sucrose (table sugar), and iodine, are solids that are composed of neutral molecules as their constituent units. These molecules are held together by weak intermolecular forces such as London dispersion forces, dipole-dipole interactions, or hydrogen bonds, which...
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Molecular Comparison of Gases, Liquids, and Solids02:26

Molecular Comparison of Gases, Liquids, and Solids

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Particles in a solid are tightly packed together (fixed shape) and often arranged in a regular pattern; in a liquid, they are close together with no regular arrangement (no fixed shape); in a gas, they are far apart with no regular arrangement (no fixed shape). Particles in a solid vibrate about fixed positions (cannot flow) and do not generally move in relation to one another; in a liquid, they move past each other (can flow) but remain in essentially constant contact; in a gas, they move...
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Updated: Jan 29, 2026

Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications
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Solid-state Graft Copolymer Electrolytes for Lithium Battery Applications

Published on: August 12, 2013

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Interfase de electrolito sólido entrelazado por gradiente a través de la reconfiguración espacial para ánodos de

Mingxue Zuo1, Xia Hu1, Changzhi Ji2

  • 1Shandong Key Laboratory of Advanced Electrochemical Energy Storage Technologies, College of New Energy, China University of Petroleum (East China), Qingdao 266580, China.

Journal of the American Chemical Society
|January 28, 2026
PubMed
Resumen
Este resumen es generado por máquina.

Diseñó una interfase de electrolito sólido (SEI) "mortise-tenon" utilizando ciclotetrasiloxano para ánodos de silicio en baterías de estado sólido (SSB). Esto estabiliza la interfaz del electrodo, permitiendo el almacenamiento de energía de alta capacidad y larga vida útil.

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Metal-Assisted Electrochemical Nanoimprinting of Porous and Solid Silicon Wafers
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Metal-Assisted Electrochemical Nanoimprinting of Porous and Solid Silicon Wafers
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Metal-Assisted Electrochemical Nanoimprinting of Porous and Solid Silicon Wafers

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Área de la Ciencia:

  • Ciencia de los materiales Ciencia de los materiales.
  • La electroquímica es electroquímica.
  • Tecnología de la batería Tecnología de la batería

Sus antecedentes:

  • Los ánodos de silicio ofrecen una alta densidad de energía para las baterías de estado sólido (SSB).
  • La expansión del volumen de los ánodos de silicio causa la fractura de interfase de electrolito sólido (SEI) y la inestabilidad de la interfaz.
  • Las interfaces rígidas en SSB carecen de amortiguación mecánica para los cambios de volumen.

Objetivo del estudio:

  • Desarrollar una estructura SEI estable para ánodos de silicio en SSB.
  • Para abordar el desafío de la fractura SEI y la inestabilidad del electrodo durante el ciclo.
  • Mejorar el rendimiento y la vida útil de los SSB basados en silicio.

Principales métodos:

  • Se introdujo ciclotetrasiloxano en electrolitos poliméricos para crear una estructura SEI "mortise-tenon".
  • Logrado el entrelazamiento entre el ciclotetrasiloxano y la fase inorgánica rica en LiF para la estabilidad de SEI.
  • Fabricado y probado con celdas semicelulares y celdas completas NCM811 y LFP.

Principales resultados:

  • El SEI "mortise-tenon" demostró una sólida adherencia y estabilidad estructural bajo grandes cambios de volumen.
  • Las semicélulas de SijedejedejedeLi lograron una alta capacidad de 1553.6 mAh g-1 a 12 A g-1.
  • Las células completas exhibieron una excelente retención de capacidad (97,6% durante 300 ciclos para NCM811 red redimido si) y bajas tasas de desintegración (0,07 ‰ por ciclo para LFP redimido si) durante 700 ciclos.

Conclusiones:

  • La estrategia de ingeniería SEI desarrollada estabiliza efectivamente los ánodos de silicio en SSB.
  • Este enfoque permite la aplicación práctica de SSBs basados en silicio de alta densidad energética.
  • El "mortise-tenon" SEI proporciona un camino para soluciones de almacenamiento de energía duraderas y de alto rendimiento.