Video Experimental Relacionado
Updated: Feb 7, 2026

Application of Elemental Lanthanides in the Selective C-F Activation of Trifluoromethylated Benzofulvenes Providing Access to Various Difluoroalkenes
Published on: July 28, 2018
Acidez de Lewis impulsada por cromismo de fluorescencia en un MOF de lantánido para la detección altamente selectiva
Tianxing Wang1, Xinhui Dong1, Yishan Hou1
1School of Nuclear Science and Technology, Xi'an Jiaotong University, Xi'an 710049, PR China. cuiyunyi@stu.xjtu.edu.cn.
Abstract:
A fluorochromic Eu-based MOF is developed for highly selective Zr(IV) detection. Leveraging the strong Lewis acidity of Zr(IV), competitive coordination to carboxylate sites induces framework dissociation, disrupts ligand-to-metal energy transfer, and produces a distinct red-to-blue luminescence shift, enabling sensitive and selective sensing with a detection limit of 333 nM.
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