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Dry Oxidation and Vacuum Annealing Treatments for Tuning the Wetting Properties of Carbon Nanotube Arrays
Published on: April 15, 2013
Aumento de la autooxidación de nanotubos de carbono en aire mediado por sal
Shohei Horike1,2,3, Kaho Kawasaki1, Yasuko Koshiba1,2
1Department of Chemical Science and Engineering, Graduate School of Engineering, Kobe University, 1-1 Rokkodai-cho, Kobe 657-8501, Japan. horike@crystal.kobe-u.ac.jp.
Abstract:
We demonstrate a strategy for p-type doping of carbon nanotubes (CNTs) by enhancing their autoxidation in air using lithium bis(trifluoromethylsulfonyl)imide (Li:TFSI). The salt promotes oxygen-mediated electron withdrawal without acting as an oxidant itself. This approach produces air-stable, highly conductive CNTs without aggressive oxidants, offering a robust route for molecular electronics.

