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Updated: Feb 28, 2026

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Ajuste de la reactividad de una unidad de osmio-peroxo mediante la modulación de la aromaticidad del metalociclo

Zhihong Deng1, Hong Zhang2, Ming Luo1

  • 1Shenzhen Grubbs Institute, Department of Chemistry, Southern University of Science and Technology, Shenzhen, 518055, China. luom3@sustech.edu.cn.

Chemical communications (Cambridge, England)
|February 27, 2026
PubMed
Resumen

La disminución de la aromaticidad en los metalociclos mejora la reactividad del osmio-peroxo. Los complejos de osmio-peroxo menos aromáticos se convierten fácilmente en complejos de hidroxo de osmio, lo que ofrece una estrategia para ajustar la reactividad de las especies de metal-oxígeno.

Palabras clave:
osmioperoxometalocicloaromaticidadreactividadhidroxocatálisisquímica organometálicaquímica inorgánica

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