C T Black1, C B Murray, R L Sandstrom

  • 1IBM Research Division, T. J. Watson Research Center, Yorktown Heights, NY 10598, USA. ctblack@us.ibm.com

Science (New York, N.Y.)
|November 10, 2000
PubMed
まとめ

コバルトナノ結晶配列は,スピン依存の電子輸送を示しています. 彼らの磁気抵抗は低温で10%に達し,より高い温度ではスピンフリップ分散によって制限されます.

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To explain the observed behavior of transition metal complexes (such as colors), a model involving electrostatic interactions between the electrons from the ligands and the electrons in the unhybridized d orbitals of the central metal atom has been developed. This electrostatic model is crystal field theory (CFT). It helps to understand, interpret, and predict the colors, magnetic behavior, and some structures of coordination compounds of transition metals.
CFT focuses on...
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Colors and Magnetism

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Spin–Spin Coupling: Three-Bond Coupling (Vicinal Coupling)

Vicinal or three-bond coupling is commonly observed between protons attached to adjacent carbons. Here, nuclear spin information is primarily transferred via electron spin interactions between adjacent C‑H bond orbitals. This generally favors the antiparallel arrangement of spins, so 3J values are usually positive.
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