pd(II) とpt(II) の角とダイアザディベンゾペリレンブリッジリングリガンドに基づく金属上分子組成の三角正方形の平衡

A Sautter1, D G Schmid, G Jung

  • 1Department of Organic Chemistry II, University of Ulm, Albert-Einstein-Allee 11, D-89081 Ulm, Germany.

まとめ

研究者は,パラジウムとプラチナでテトラアリロキシ代用ダイアザジベンゾペリレンリガンドを用いて,分子三角形と正方形の間の動的均衡を調査した. リガンドのステリック・バルクは,正方形を好み,組立形成に影響を与えました. これは,金属超分子自己組み立ての重要な要因を明らかにします.

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