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Updated: Jul 16, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
10:51

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes

Published on: April 10, 2015

[ (テルピー) ] (H2O) Mn (III) (O) 2 Mn (IV) (OH2) (テルピー) ] (NO3) 3 (テルピー = 2,2':6,2"-テルピリジン) によって触媒化されたO (O2) を生成する反応の特徴)

J Limburg1, J S Vrettos, H Chen

  • 1Contribution from the Department of Chemistry, Yale University, P.O. Box 208107, New Haven, Connecticut, 06520-8107, USA.

Journal of the American Chemical Society
|July 18, 2001
PubMed
まとめ

この研究は,光合成による水の酸化を模倣して,オクソンとヒポクロライトから酸素の進化を触媒するマンガン複合体を実証しています. この研究は,酸素生成の理解に不可欠な,Mn(V) = O の中間物質を含むメカニズムを提案しています.

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