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Updated: Jun 24, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 21, 2014

Pd触媒による,一酸化炭素との交代共ポリメリゼーションにおいて,スタイロンの1,2挿入が優勢である

K Nozaki1, H Komaki, Y Kawashima

  • 1Department of Material Chemistry, Graduate School of Engineering, Kyoto University, Sakyo-ku, Kyoto 606-8501 Japan.

Journal of the American Chemical Society
|July 18, 2001
PubMed
まとめ

この研究は,他のリガンドとは対照的に,COとパラジアム触媒共ポリメリゼーションにおけるスタイレン1,2挿入を独占的に明らかにしています. この地域選択性はβ-ヒドリドの除去を防止し,制御されたポリマー鎖の成長を可能にします.

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