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Dissolution Dynamic Nuclear Polarization Instrumentation for Real-time Enzymatic Reaction Rate Measurements by NMR
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Dissolution Dynamic Nuclear Polarization Instrumentation for Real-time Enzymatic Reaction Rate Measurements by NMR

Published on: February 23, 2016

安定状態以外の条件下でのニトロアルカンと水酸化イオン間の陽子転移反応. 表面的および実際の運動性同位体効果

Y Zhao1, Y Lu, V D Parker

  • 1Department of Chemistry and Biochemistry, Utah State University, Logan, Utah 84322-0300, USA.

Journal of the American Chemical Society
|July 18, 2001
PubMed
まとめ

1-nitro-1-(4-nitrophenyl) ethane (NNPE) と水酸化イオンを含む陽子伝達反応は,複雑な運動学を示し,重要な陽子トンネリングを含む多段階メカニズムを示しています. 動的同位体効果は,この複雑な反応経路を確認する.

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