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Updated: Jun 24, 2026

Site Directed Spin Labeling and EPR Spectroscopic Studies of Pentameric Ligand-Gated Ion Channels
11:19

Site Directed Spin Labeling and EPR Spectroscopic Studies of Pentameric Ligand-Gated Ion Channels

Published on: July 4, 2016

メチルインダノンの電子移転誘発型タウトメリゼーション:エノライゼーションのトンネリング速度の電子制御

P Bednarek1, Z Zhu, T Bally

  • 1Contribution from the Institute of Physical Chemistry, University of Fribourg, Perolles, CH-1700 Fribourg, Switzerland.

Journal of the American Chemical Society
|July 18, 2001
PubMed
まとめ

メチル群の位置は,リモートメチル群の電子効果により,より反応性の低い状態を安定させることで,ラジカルカチオンエノライゼーションの速度に大きく影響します. 量子計算は,トンネルバリアを通してこれらの運動的差異を説明します.

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