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Updated: Jun 29, 2026

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes
10:51

The Synthesis, Characterization and Reactivity of a Series of Ruthenium N-triphosPh Complexes

Published on: April 10, 2015

三座標モリブデン (III) 複合体による選択的酸化窒素N-N結合割れの起源について

J P Cherry1, A R Johnson, L M Baraldo

  • 1Contribution from the Departments of Chemistry, Room 2-227, Massachusetts Institute of Technology, Cambridge, Massachusetts 02139-4307, USA.

Journal of the American Chemical Society
|July 27, 2001
PubMed
まとめ

モリブデン複合体は,酸化窒素と反応してニトリドおよびニトロシル製品を形成しますが,予想されるオクソ複合体ではありません. この反応は運動制御下にあり,リガンドのステリック効果の影響を受けた二金属N-N結合分裂機構を示唆する.

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