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Updated: Jun 21, 2026

Structure and Coordination Determination of Peptide-metal Complexes Using 1D and 2D 1H NMR
14:44

Structure and Coordination Determination of Peptide-metal Complexes Using 1D and 2D 1H NMR

Published on: December 16, 2013

同じ金属断片の複合体の構造を,C,C-およびC,O結合モードの両方でケテンと直接比較したのが初めて

D B Grotjahn1, L S Collins, M Wolpert

  • 1Department of Chemistry, 5500 Campanile Drive, San Diego State University, San Diego, CA 92182-1030, USA.

Journal of the American Chemical Society
|August 23, 2001
PubMed
まとめ

この研究は,イリジウム (Ir) とロジウム (Rh) のケテン複合体における金属リガンド結合がケテン結合モードによってどのように異なるかを明らかにしています. これは,Ir複合体におけるより大きなトランス影響とバックボンドを強調し,ケテンリガンド化学を理解するのに役立ちます.

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