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関連する概念動画

Chemical Reactions01:19

Chemical Reactions

A chemical reaction is a process by which the bonds in the atoms of substances are rearranged to generate new substances. Matter cannot be created or destroyed in a chemical reaction—the same type and number of atoms that make up the reactants are still present in the products. Merely, the rearrangement of chemical bonds produces new compounds.
Chemical Reactions Rearrange Atoms into New Substances
A chemical reaction takes starting materials—the reactants—and changes them into different...
Synthesis and Decomposition Reactions02:17

Synthesis and Decomposition Reactions

Synthesis and decomposition are two types of redox reactions. Synthesis means to make something, whereas decomposition means to break something. The reactions are accompanied by chemical and energy changes.
Chemical Reactions02:26

Chemical Reactions

A balanced chemical equation provides the information of chemical formulas of the reactants and products involved in the chemical change. A reaction’s stoichiometry helps predict how much of the reactant is needed to produce the desired amount of product, or in some cases, how much product will be formed from a specific amount of the reactant.
The relative amounts of reactants and products represented in a balanced chemical equation are often referred to as stoichiometric amounts. However, in...
SN2 Reaction: Mechanism02:27

SN2 Reaction: Mechanism

The kinetic studies of SN2 reactions suggest an essential feature of its mechanism: it is a single-step process without intermediates. Here, both the nucleophile and the substrate participate in the rate-determining step.
The presence of the more electronegative halogen in the substrate creates a polarized carbon-halide bond. The halide pulls the electron cloud generating an electrophilic center at the carbon atom. Thus, the carbon atom carries a partial positive charge while the halide has a...
Introduction to Chemical Reactions01:23

Introduction to Chemical Reactions

All chemical reactions begin with a reactant, the general term for one or more substances entering the reaction. Sodium and chloride ions, for example, are the reactants in the production of table salt. One or more substances produced by a chemical reaction are called the product. Chemical reactions follow the law of conservation of mass, which means that matter cannot be created nor destroyed in a chemical reaction. The components of the reactants—the number of atoms and the elements—are all...
Types of Chemical Reactions: Exchange and Reversible01:08

Types of Chemical Reactions: Exchange and Reversible

An exchange reaction is a chemical reaction in which both synthesis and decomposition occur, chemical bonds are both formed and broken, and chemical energy is absorbed, stored, and released.
A special kind of exchange reaction is the oxidation-reduction reaction, or the redox reaction. These reactions involve the transfer of electrons from one compound to another. The electrons in these reactions commonly come from hydrogen atoms, which consist of an electron and a proton. A molecule gives up a...

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関連する実験動画

Updated: Jul 17, 2026

Utilization of Stop-flow Micro-tubing Reactors for the Development of Organic Transformations
13:09

Utilization of Stop-flow Micro-tubing Reactors for the Development of Organic Transformations

Published on: January 4, 2018

固体/固体有機反応の理解

G Rothenberg1, A P Downie, C L Raston

  • 1York Green Chemistry Group, Chemistry Department, University of York, Heslington, York YO10 5DD, UK.

Journal of the American Chemical Society
|September 6, 2001
PubMed
まとめ

ほとんどの固体相有機反応は,固体反応物を研磨することで形成される液相を含んでいる. このユーテクティックな混合物形成は反応運動を説明し,真の固体相反応の概念に異議を唱える.

科学分野:

  • 有機化学 オーガニック・ケミストリー
  • マテリアルサイエンス 材料科学
  • 物理化学 物理化学

背景:

  • 固体粒子の間の有機反応を調査することは,新しい合成方法論の開発に不可欠です.
  • 多くの反応が固体相で起こることが報告されていますが,そのメカニズムは明確にする必要があります.

研究 の 目的:

  • 固体相有機反応の概念を調査する.
  • 固体反応物の間の反応における相変化の役割を決定する.

主な方法:

  • 19件の報告された"固体相"有機反応の分析.
  • 固体反応物の機械的混合 (研磨) を行う.
  • 相変化 (液化) と反応運動学の観察.

主要な成果:

  • 固体反応物質を研磨すると,通常は液体相を形成し,通常は周囲の温度より低い融点を持つエウテクティック混合物になります.
  • この液化は,アルドール凝縮,ベイヤー-ヴィリガー酸化,芳香ブロミネーションを含む,触媒的および非触媒的反応の両方で発生します.
  • 観測された反応動態は,固体相から液体相への移行によって説明される.

結論:

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Performing In Situ Closed-Cell Gas Reactions in the Transmission Electron Microscope

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Fluid-cell Raman Spectroscopy for operando Studies of Reaction and Transport Phenomena during Silicate Glass Corrosion
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Fluid-cell Raman Spectroscopy for operando Studies of Reaction and Transport Phenomena during Silicate Glass Corrosion

Published on: May 9, 2025

関連する実験動画

Last Updated: Jul 17, 2026

Utilization of Stop-flow Micro-tubing Reactors for the Development of Organic Transformations
13:09

Utilization of Stop-flow Micro-tubing Reactors for the Development of Organic Transformations

Published on: January 4, 2018

Performing In Situ Closed-Cell Gas Reactions in the Transmission Electron Microscope
14:21

Performing In Situ Closed-Cell Gas Reactions in the Transmission Electron Microscope

Published on: July 24, 2021

Fluid-cell Raman Spectroscopy for operando Studies of Reaction and Transport Phenomena during Silicate Glass Corrosion
06:48

Fluid-cell Raman Spectroscopy for operando Studies of Reaction and Transport Phenomena during Silicate Glass Corrosion

Published on: May 9, 2025

  • マクロスコープの粒子の間の真の固体相反応は稀であり,液化は一般的な現象である.
  • ユーテクティックまたはペリテクティック形成は,固体反応物の機械的混合を含む反応を理解するための鍵です.
  • 固体反応剤を含む反応性システムの一般的なモデルは,潜在的な液相形成を考慮する必要があります.