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Updated: Jul 30, 2026

Synthesis and Characterization of Functionalized Metal-organic Frameworks
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C-F...M(+) 相互作用に関する研究:フッ素を含むケージ化合物の金属複合体

H Takemura1, S Nakashima, N Kon

  • 1Department of Chemistry, Faculty of Science, Kyushu University, Ropponmatsu 4-2-1, Chuo-ku, Fukuoka, 810-8560 Japan.

Journal of the American Chemical Society
|September 20, 2001
PubMed
まとめ

カチオン二極力によって引き起こされるC-F...M(+) 相互作用は,NMRと結晶学を用いたケージ化合物で確認されました. 複合的な安定性は,硬軟の相互作用ではなく,金属カチオンの性質に依存し,フッ素ベンゼンに関する洞察を明らかにします.

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