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Updated: Jul 15, 2026

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers
08:12

Depolymerizable Olefinic Polymers Based on Fused-Ring Cyclooctene Monomers

Published on: December 16, 2022

半サンドイッチのMo (III) /Mo (IV) カップルによって制御されるスタイレンの急性ポリメリゼーション:すべての基本的なメカニズムが可能です

E Le Grognec1, J Claverie, R Poli

  • 1Laboratoire de Synthèse et d'Electrosynthèse Organométalliques, Faculté des Sciences Gabriel, Université de Bourgogne, 6 Boulevard Gabriel, 21000 Dijon, France.

Journal of the American Chemical Society
|September 27, 2001
PubMed
まとめ

密度関数計算は,安定したフリーラジカルポリメリゼーション (SFRP) または原子移転ラジカルポリメリゼーション (ATRP) による制御されたスタイレンポリメリゼーションのためのモリブデン複合体の選択をガイドしました. これらの複合体は制御されたポリメリゼーションを可能にし,反応条件に応じて触媒連鎖移転を示すものもあります.

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