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Updated: Jul 9, 2026

A Kinetic Fluorescence-based Ca2+ Mobilization Assay to Identify G Protein-coupled Receptor Agonists, Antagonists, and Allosteric Modulators
07:41

A Kinetic Fluorescence-based Ca2+ Mobilization Assay to Identify G Protein-coupled Receptor Agonists, Antagonists, and Allosteric Modulators

Published on: February 20, 2018

アリファティックおよびアロマティック炭素-フッ素結合の活性化でCp*(2) ZrH(2):水酸化フッ素化のメカニズム

B M Kraft1, R J Lachicotte, W D Jones

  • 1Department of Chemistry, University of Rochester, Rochester, NY 14627, USA.

Journal of the American Chemical Society
|November 1, 2001
PubMed
まとめ

Cp*(2) ZrH(2) は,リジカルチェーンメカニズムを通じて,アリファティック炭化水素からフッ素を定量的に除去し,より多くの置換炭化水素に対して反応性が低下します. 芳香C−F結合は,ヒドリド攻撃またはC−H活性化を含む異なる経路で反応する.

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