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Updated: Aug 11, 2026

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions
11:44

Mizoroki-Heck Cross-coupling Reactions Catalyzed by Dichloro{bis[1,1',1''-(phosphinetriyl)tripiperidine]}palladium Under Mild Reaction Conditions

Published on: March 20, 2014

モノデンテートリガンドによる高度にエナンチオセレクティブな分子内ヘック反応

Rosalinde Imbos1, Adriaan J Minnaard, Ben L Feringa

  • 1Stratingh Institute, Department of Organic Chemistry, University of Groningen, Nijenborgh 4, 9747 AG Groningen, The Netherlands.

Journal of the American Chemical Society
|January 10, 2002
PubMed
まとめ

TADDOLベースのフォスフォラミドイトリガンドを使用した新しいエナンチオセレクティブの分子内ヘック反応は,キラルサイクロヘキサディエノンを効率的に生成します. この方法では,高エナチオセレクティビティ (96% ee) が達成され,ヘック反応におけるモノデントリガンドとしては初めてである.

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