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Updated: Jul 1, 2026

Iridium(III) Luminescent Probe for Detection of the Malarial Protein Biomarker Histidine Rich Protein-II
12:52

Iridium(III) Luminescent Probe for Detection of the Malarial Protein Biomarker Histidine Rich Protein-II

Published on: July 7, 2015

電子と媒体の影響は,カチオンのIr (III) 複合体によるアレンC[bond]H活性化の速度に影響する

David M Tellers1, Cathleen M Yung, Bruce A Arndtsen

  • 1Division of Chemical Sciences, Lawrence Berkeley National Laboratory, University of California, Berkeley, California 94720, USA.

Journal of the American Chemical Society
|February 14, 2002
PubMed
まとめ

この研究では,イリジウム複合体は,イオンペアメカニズムを通じてアレン内のC-H結合を活性化させ,トリフラート解離が活性化に先行することを明らかにしました. 反応性は,イリジウム複合体とアレン基板の両方の電子ドナー置換物によって強化されます.

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