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Updated: Jun 26, 2026

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes
12:27

Synthesis of Hypervalent Iodonium Alkynyl Triflates for the Application of Generating Cyanocarbenes

Published on: September 8, 2013

レニウムアルキニルカルベンの複合体からシス-エネディイン複合体の形成

Charles P Casey1, Stefan Kraft, Douglas R Powell

  • 1Department of Chemistry, University of Wisconsin, Madison, WI 53706, USA.

Journal of the American Chemical Society
|March 14, 2002
PubMed
まとめ

レニウムアルキニルカルベンの複合体は二分化され,エネディイン複合体を形成する. この研究では,二分化機構を調査し,結合複合体および拘束複合体の急速な反応を明らかにし,ビニルカルベンの中間物質を含む提案されたメカニズムをサポートしています.

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