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Updated: Jul 17, 2026

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units
09:35

Preparation of a Corannulene-functionalized Hexahelicene by Copper(I)-catalyzed Alkyne-azide Cycloaddition of Nonplanar Polyaromatic Units

Published on: September 18, 2016

トンネリングとステリカルに誘発されたリングパッカリングは,代用された [8]アヌレンのアニオンラジカルでアヌレンのアニオンラジカルを入れ替えた [8]アヌレンのアニオンラジカルを入れ替えた

Cheryl D Stevenson1, Lance J Heinle, John P Davis

  • 1Department of Chemistry, Illinois State University, Normal, IL 61790-4160, USA.

Journal of the American Chemical Society
|March 14, 2002
PubMed
まとめ

tert-butoxy-cyclooctatetraeneアニオンラジカルにおけるステリック相互作用は,リングパッカリングを引き起こし,EPR結合定数を減少させます. デュテレーションは,この効果を弱め,結合定数を増加させ,量子トンネリングによる可能性のある急速な形状の変化を示唆する.

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