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Updated: Jul 6, 2026

Using Polystyrene-block-poly(acrylic acid)-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization
09:02

Using Polystyrene-block-poly(acrylic acid)-coated Metal Nanoparticles as Monomers for Their Homo- and Co-polymerization

Published on: July 9, 2015

イソタクティック-b-シンディオタクティックステレオブロックポリ (メチルメタクリlate) は,キラルメタルロゼン/ルイス酸ハイブリッド触媒による

Andrew D Bolig1, Eugene Y-X Chen

  • 1Department of Chemistry, Colorado State University, Fort Collins, Colorado 80523-1872, USA.

Journal of the American Chemical Society
|May 16, 2002
PubMed
まとめ

キラル触媒は,メチルメタクリラートのステレオブロックポリメリゼーションを可能にし,交互に異質質と合成質のセグメントを交互に持つポリマーを作成します. このブレークスルーにより,高度な材料の応用のために,ポリマーマイクロ構造を正確に制御することができます.

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Formation of Complex Ions

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Metal-Ligand Bonds

The hemoglobin in the blood, the chlorophyll in green plants, vitamin B-12, and the catalyst used in the manufacture of polyethylene all contain coordination compounds. Ions of the metals, especially the transition metals, are likely to form complexes.
In these complexes, transition metals form coordinate covalent bonds, a kind of Lewis acid-base interaction in which both of the electrons in the bond are contributed by a donor (Lewis base) to an electron acceptor (Lewis acid). The Lewis acid in...
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Complexation Equilibria: The Chelate Effect

In complexation reactions, metal atoms or cations interact with ligands to form donor-acceptor adducts called metal complexes. Ligands that bind through one donor site are monodentate, ligands with two donor sites are bidentate, and those with more than two donor sites are polydentate ligands. For example, ethylene diamine is a bidentate ligand that binds through two nitrogen donor atoms, forming a five-membered ring. EDTA is a polydentate ligand that binds through four oxygen and two nitrogen...
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Complexometric Titration: Ligands

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Heterogeneous Catalysis

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