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関連する概念動画

Hydrogen Bonds00:26

Hydrogen Bonds

Hydrogen BondsHydrogen bonds are weak attractions between atoms that have formed other chemical bonds. One of these atoms is electronegative, like oxygen, and has a partial negative charge. The other is a hydrogen atom that has bonded with another electronegative atom and has a partial positive charge.Hydrogen Bonds Control the World!Because hydrogen has very weak electronegativity when it binds with a strongly electronegative atom, such as oxygen or nitrogen, electrons in the bond are...
Cohesion01:07

Cohesion

Cohesion is the attraction between molecules of the same type, such as water molecules. Water molecules have an overall neutral charge but are polar molecule. An oxygen atom in one water molecule has a partial negative charge that can bind to a hydrogen atom with a partial positive charge in a second water molecule, forming a hydrogen bond. Each water molecule can form up to four hydrogen bonds with other water molecules. Hydrogen bonds are responsible for water's cohesive nature.
On a surface,...
Intermolecular Forces03:13

Intermolecular Forces

Atoms and molecules interact through bonds (or forces): intramolecular and intermolecular. The forces are electrostatic as they arise from interactions (attractive or repulsive) between charged species (permanent, partial, or temporary charges) and exist with varying strengths between ions, polar, nonpolar, and neutral molecules. The different types of intermolecular forces are ion–dipole, dipole–dipole, hydrogen bonds, and dispersion; among these, dipole–dipole, hydrogen bonds, and dispersion...
Intermolecular Forces and Physical Properties02:56

Intermolecular Forces and Physical Properties

Hydrogen Bonds01:04

Hydrogen Bonds

A hydrogen bond is formed when a weakly positive hydrogen atom already bonded to one electronegative atom (for example, the oxygen in the water molecule) is attracted to another electronegative atom from another polar molecule, such as water (H2O), hydrogen fluoride (HF), or ammonia (NH3). The huge electronegativity difference between the H atom (2.1) and the atom to which it is bonded (4.0 for an F atom, 3.5 for an O atom, or 3.0 for an N atom), combined with the very small size of an H atom...
Surface Tension01:24

Surface Tension

Surface tension is defined as the force per unit length (γ) acting along the surface of a liquid. It arises due to strong intermolecular forces of attraction. A molecule located inside the bulk of the liquid is surrounded by other molecules and experiences equal forces in all directions. However, a molecule at the surface experiences unbalanced forces because there are more neighboring molecules below than above. This creates a net inward force that pulls surface molecules toward the interior,...

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関連する実験動画

Updated: Jul 13, 2026

Synthesis and Characterization of Supramolecular Colloids
09:26

Synthesis and Characterization of Supramolecular Colloids

Published on: April 22, 2016

表面力,超分子ポリマー,逆対称性

Jasper van der Gucht1, Nicolaas A M Besseling, Martien A Cohen Stuart

  • 1Dutch Polymer Institute/Wageningen University, Laboratory of Physical Chemistry and Colloid Science, Dreijenplein 6, 6703 HB Wageningen, The Netherlands. jasper@fenk.wau.nl

Journal of the American Chemical Society
|May 23, 2002
PubMed
まとめ

超分子均衡ポリマーは,表面力を大幅に変化させます. モノメアの方向性は,力が吸引力か排斥力かを決定し,材料設計の新たな可能性を提供します.

科学分野:

  • ポリマーサイエンスの科学
  • 表面化学について
  • 物理化学 物理化学

背景:

  • 均衡ポリマーは,可逆結合によって形成されるダイナミックなポリマーネットワークです.
  • 表面力に対するそれらの影響を理解することは,先進的な材料にとって極めて重要です.
  • 既存のモデルは,しばしば,超分子ポリマーのユニークな性質を考慮していない.

研究 の 目的:

  • 表面力に対する超分子均衡ポリマーの影響を調査する.
  • 平衡ポリマーによって生成される表面力を従来のポリマーから区別するために.
  • モノメア構造の役割,特に対称性と方向性を,これらの力を決定する上で探求する.

主な方法:

  • 現象学的ランдау型分析.
  • ベーテ・グッゲンハイム近似を用いた分子モデリング.
  • 対称性 (B-B) と非対称性 (A-D) のモノマーによって生成される力の比較.

主要な成果:

  • 均衡ポリマーは,通常のポリマーとは異なる表面力を誘導することができる.
  • シンメトリックなモノマーは,非方向的な鎖と表面間の引き寄せ力を生み出します.
  • 非対称なモノマーは方向性鎖を作り,その結果,強い反発力が生じます.

さらに関連する動画

Covalent Immobilization of Proteins for the Single Molecule Force Spectroscopy
11:13

Covalent Immobilization of Proteins for the Single Molecule Force Spectroscopy

Published on: August 20, 2018

Covalent Attachment of Single Molecules for AFM-based Force Spectroscopy
10:37

Covalent Attachment of Single Molecules for AFM-based Force Spectroscopy

Published on: March 16, 2020

関連する実験動画

Last Updated: Jul 13, 2026

Synthesis and Characterization of Supramolecular Colloids
09:26

Synthesis and Characterization of Supramolecular Colloids

Published on: April 22, 2016

Covalent Immobilization of Proteins for the Single Molecule Force Spectroscopy
11:13

Covalent Immobilization of Proteins for the Single Molecule Force Spectroscopy

Published on: August 20, 2018

Covalent Attachment of Single Molecules for AFM-based Force Spectroscopy
10:37

Covalent Attachment of Single Molecules for AFM-based Force Spectroscopy

Published on: March 16, 2020

結論:

  • モノメアの方向性は,均衡状態のポリマー系における表面力の性質と範囲を制御する重要な要因である.
  • 吸引力と排斥力の濃度依存性は,モノマー対称性に基づいて著しく異なる.
  • これらの発見は,調節可能な表面相互作用を持つ材料を設計するための道を開きます.