混合バレンスの複合体における電子伝送速度の溶媒動的制御は,赤外線スペクトル線形状の凝結によって観測される

Casey H Londergan1, J Catherine Salsman, Silvia Ronco

  • 1Department of Chemistry and Biochemistry, University of California, San Diego, La Jolla, California 92093-0358, USA.

まとめ

赤外線スペクトロスコーピーは,ルテニウム複合体の電子伝送速度が溶媒の放緩と相関していることを明らかにしています. これにより,定常状態のIRスペクトルは,超高速の溶媒ダイナミクスを探査することができます.

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