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Updated: Jul 25, 2026

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators
06:31

Highly Stereoselective Synthesis of 1,6-Ketoesters Mediated by Ionic Liquids: A Three-component Reaction Enabling Rapid Access to a New Class of Low Molecular Weight Gelators

Published on: November 27, 2015

機能化されたキラルアルケンのダイアステロセレクティブシラクロプロパネーションである

Tom G Driver1, Annaliese K Franz, K A Woerpel

  • 1Department of Chemistry, University of California, Irvine, California 92697-2025, USA.

Journal of the American Chemical Society
|June 6, 2002
PubMed
まとめ

リチウム還元と熱シリレン転送により,キラルオレフィンの高度にダイアステロセレクティブなシリサイクロプロパネーションが可能になります. 酸素効果ではなく,ステリック要因が反応を左右する.

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