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Updated: Jul 28, 2026

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions
19:58

Palladium N-Heterocyclic Carbene Complexes: Synthesis from Benzimidazolium Salts and Catalytic Activity in Carbon-carbon Bond-forming Reactions

Published on: July 30, 2017

アルファ-アゴスティックなSi[bond]H相互作用を有するカチオニウムハフニウムシリル複合体によってアレンC[bond]H結合の活性化

Aaron D Sadow1, T Don Tilley

  • 1Department of Chemistry, University of California, Berkeley, Berkeley, California 94720-1460, USA.

Journal of the American Chemical Society
|June 13, 2002
PubMed
まとめ

Zwitterionic ハフニウムシリル複合体は,芳香C-H結合を活性化する. この反応は協調された移行状態を経由して進行し,新たな有機金属反応性およびC-H結合機能化の経路に関する洞察を提供している.

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