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Updated: Jul 18, 2026

The Preparation and Properties of Thermo-reversibly Cross-linked Rubber Via Diels-Alder Chemistry
07:02

The Preparation and Properties of Thermo-reversibly Cross-linked Rubber Via Diels-Alder Chemistry

Published on: August 25, 2016

タンタールとアロマティックリングの間の反転可能な分子内ヒドリド移転:マスクされたヒドリドとしてエタ(5) -サイクロヘキサジニル複合体

John Gavenonis1, T Don Tilley

  • 1Department of Chemistry, University of California, Berkeley, Berkeley, California 94720-1460, USA.

Journal of the American Chemical Society
|July 18, 2002
PubMed
まとめ

タンタール複合体は水素と反応し,エタ5-サイクロヘキサジニル複合体を形成する. この反応は,触媒性水素化における重要なステップである金属水素結合へのアレン環挿入を実証し,可逆性を示しています.

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