ラメラー・メソファゼとコラムナー・メソファゼの間の再エントラント・イソトロピック相
Urszula Pietrasik1, Jadwiga Szydłowska, Adam Krówczyński
1Chemistry Department, Warsaw University, Laboratory of Dielectrics and Magnetics, Al. Zwirki i Wigury 101, 02-089 Warsaw, Poland.
Journal of the American Chemical Society
|July 26, 2002
まとめ
合成されたニッケル (II) 複合体と分子内水素結合は,ユニークな液晶特性を有する. コラムナー・フェーズとラメラー・フェーズの間には,初めて同otropicの再侵入フェーズが観察されました.
科学分野:
- 協調化化学について
- マテリアルサイエンス 材料科学
- 液体結晶は,液体結晶から成る.
背景:
- テトラデンタルシス-エナミノケトンNi (II) コンプレックスが合成されました.
- 分子内の水素結合が導入され,分子構造と性質が変更されました.
研究 の 目的:
- 分子形状と水素結合がNi (II) 複合体の液晶性行為に及ぼす影響を調査する.
- 合成化合物における新しい相配列を探求する.
主な方法:
- テトラデンタルシス-エナミノケトンNi (II) 複合体の合成.
- 分子構造と相行動の特徴化.
主要な成果:
- 分子内水素結合とアルコキシ端末鎖を持つ複合体は,珍しい相配列を示した:Iso-D(h) -Iso(re) -SmA.
- 列状 (D) 及び板状 (SmA) 段階を分離する同otropic re-entrant (Iso(re)) 段階が初めて観察されました.
結論:
- 分子内水素結合は,Ni (II) 複合体のメソゲン特性に大きな影響を与える.
- コラムナー・フェーズとラメラー・フェーズ間のアイソトロピック・リエントラント・フェーズを発見したことで,液晶・フェーズ・トランジションに関する新しい洞察が得られる.
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