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Updated: Apr 22, 2026

[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst
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[DPEPhosbcpCu]PF6: A General and Broadly Applicable Copper-Based Photoredox Catalyst

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ベンジル/トロウエネ,メトキシル/メタノール,フェノキシル/フェノールの自己交換反応における,陽子結合電子移転と水素原子移転の対比

James M Mayer1, David A Hrovat, Jennie L Thomas

  • 1Contribution from the Department of Chemistry, University of Washington, Box 351700, Seattle, Washington 98195-1700, USA. mayer@chem.washington.edu

Journal of the American Chemical Society
|September 13, 2002
PubMed
まとめ

密度関数理論の計算は,水素交換反応の明確なメカニズムを明らかにします. ベンジル/トルーエンおよびメトキシル/メタノール反応は,水素原子移転 (HAT) 経由で行われるが,フェノキシル/フェノルは,陽子結合電子移転 (PCET) を含む.

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